络合剂强化金盏菊修复pb cd复合对污染土壤的研究.docxVIP

(3)Pb／Cd复合胁迫下，金盏菊地上部分和地下部分干生物量均与土壤 (3)Pb／Cd复合胁迫下，金盏菊地上部分和地下部分干生物量均与土壤 持水量呈近似的倒V型曲线；在Pb／Cd单一／复合污染条件下(土壤持水量为 土壤田间持水量的65％70％(w2))，金盏菊幼苗的出苗率仍维持在45％ 以上，土壤中Pb／Cd的存在能促进金盏菊幼苗地下部分的生长，金盏菊幼苗 能够改良污染黄土的容重、pH、有机质、CEC和电导率等基本理化性质； 过高或过低的土壤持水量都不利于金盏菊幼苗对重金属的吸收积累，65％～ 70％(w2)田间持水量条件下，适宜金盏菊生长，且植物体内积累的重金 属也最多；不同土壤持水量下，土壤pH明显大于基础土壤，土壤pH与土壤 中可交换及碳酸盐结合态重金属浓度之间并没有显著的相关性，且土壤持水 量对土壤中可交换及碳酸盐结合态重金属浓度的影响也并不显著。 (4)植物地上部分和地下部分Pb／Cd含量均随采样时间增加而增加； EDTA、EDTA和酒石酸组合显著提高了金盏菊地上部分和地下部分Pb／Cd 含量，金盏菊不同部位Pb／Cd富集系数显著提高，添加EDTA后，植物Pb 转移系数大于1，但Cd转移系数仍然小于1；EDTA与酒石酸组合能显著提 高金盏菊地上部分和地下部分的重金属积累量，且EDTA、酒石酸浓度分别 为1．5mmol／kg、 O．5mmol／kg时的强化效果最好；EDTA及EDTA与酒石酸 组合处理下，土壤中可交换及碳酸盐结合态-Pb／Cd含量显著提高，且金盏 菊体内的重金属含量与土壤中可交换及碳酸盐结合态．Pb／Cd具有很好的相 关性；通过XPS分析发现，C和O是植物地上部分和地下部分含量最多的 两种元素，施用螯合剂后，地上部分O含量减小，其活性降低，不利于植 物地上部分生长。 关键词：植物修复，络合剂，Pb，Cd，金盏菊 万方数据 Studies Studies of Calendula officinalis L Strengthening with Chelants on Remediation Behavior in Co mbinative Contaminated Soil ofOl PbP andand ABSTRACT Pb and Cd were the worst or most popular pollutants in soil,respectively． They could transfer in environment t11rough dissolution，sedimentation and SO on， due to food chain and biomagnifications，Pb and Cd could harm animals and human beings health．Currently,phys ical,chemical and ecological remediation procedures were three main methods of restoration and management of Pb and Cd polluted soils．Phytorcmediation was used to remove heavy metals from the contaminated soils as an ecological technique,and the mechanism of phytoremediation Was to use hyperaccumulators or tolerant p lants to absorb， accumulate and translate heavy metals from the contaminated soils，achieving the purpose of alleviating the pollution of heavy metals．The phytorcrnediation technique had some advantages in comparison with the traditional remediation technologies，such as economical,non-pollution and high effic iency．Calendula officinalis L could tolerate low temperature to．90C．and it Was not strict with illumination,water,fertilizer and grew quickly．The tolerance to heavy m