N氮杂环甲氧基O4芳氧基苯基乳酸酰胺合成与除草活性刘祈星.pdfVIP

DOI: 10.6023/cjoc201307017 Chinese Journal of Organic Chemistry ARTICLE N--O-(4-) a,b b *,b b b b b b b *,a (a 410082) (b 410007) A8169 , 12 N--O-(4-), 1H 13 NMR, C NMR, LC/MS IR . , 2250 g/ha , (Digitaria sanguinalis)(Echinochloa crus-galli)(Setaria viridis)100%, , (R)-()-N-[(2--5-)]-O-[4-((6--2-))](2f)(IC50 6.8 g/ha, IC50 6.6 g/ha)A8169. N--O-(4-); ; Synthesis and Herbicidal Activity of Novel N-Hetrocyclo Containing Nitrogen Methoxy-O-(4-aryloxy-phenyl) Lactamide Derivatives Liu, Qixinga,b Huang, Mingzhib Liu, Aiping*,b Nie, Siqiaob Lei, Manxiangb Ren, Yeguob Pei, Huib He, Liyingb Hu, Lib Hu, Aixi*,a (a College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082) b ( National Engineering Research Center for Agrochemicals, Hunan Research Institute of Chemical Industry, Changsha 410007) Abstract The lead compound A8169 was modified, 12 N-hetrocyclo containing nitrogen methoxy-O-(4-aryloxy-phenyl) lactamide derivatives were designed and synthesized, and their structures were characterized by 1H NMR, 13C NMR, LC/MS and IR. The bioassay results indicated that all compounds exhibited 100% activities against Digitaria sanguinalis, Echinochloa crus-galli L and Setaria Viridis at 2250 g/ha. In particular, (R)-()-N-((2-chlorothiazol-5-yl)methoxy)-O-(4-((6-chloro- quinoxalin-2-yl)oxy)phenoxy) lactamide