paa纤维素复合水凝胶的制备及性能研究材料加工工程专业论文.docxVIP

ABSTRACTBacterial ABSTRACT Bacterial cellulose(BC)or microcrystalline cellulose(MCC)liquor was added to polyacrylic acid hydrogels to produce PAA／cellulose composite hydrogels·The composite hydrogel composition was determined by testing propertms such as water absorption Derforrnance，water retention properties，metal ion adsorption performance，thermal DerfoHnallce，and dynamic mechanical properties．In addition，the microstructure，chemical composition and structure of the hydrogels were characterized．The experimental results showed that the composite hydrogels performance，including water absorption，water retention．and thermal performance，increased obviously after adding the BC or MCC，and the best concentration of the BC(or MCC)was 0．6 wt％．See from IR test after adding cellulose．hydroxy peak strength，peak groups were broadly similar．We Can conclude that adding cellulose Can not introduce new characteristic peak．Results can be found by scarming electron microscopy，the cross—section porosity increased obviously after adding cellulose、but also more uniform，which made the composite hydrogels have larger storage spaoc· The different ratio of acrylamide，acrylic acid monomer and cellulose(BC，MCC) orthogonal experiment Was carried out to produce P(AA—CO—AM)／cellulose composite hydrogels．Through a series ofexperimental test results show that under the condition ofthe AM／AA were 60 wt％and 70 wt％，the highest water imbibition of composite hydrogels， and the strong ability of water retention．When BC content was 0．4 wt％，MCC content was 0．4 wt％and 0．6 wt％，the absorbent，water retention，swelling performance of the compound hydrogels Was the best．After adding cellulose，the energy storage modulus of composite hydrogels was greatly increased，and a higher degree of crystallinity,mechanical properties had universal enhancement．At the same time，the composite hydrogels had higher melting point，heat resistant performance was improved．IR test showed that acrylanfide and acrylic acid did happen