mof复合物的设计合成及其在超级电容器中的电性能研究无机化学专业论文.docxVIP

ABSTRACTMetal-Organic ABSTRACT Metal-Organic Frameworks have been the research focus for many years because of their particular porous structure and the tunable chemical components and topology．With the development more than twenty years，MOFs studies shifting from the design and synthesis ofnewly functional crystal structures to the synthesis and application ofMOF-based composites and MOF derivatives．The formation ofMOF Composite is alternative way to broaden the scope of applications for MOFs from gas absorption，separation and catalysis to new fields such sensing，drug delivery,and electrochemical applications．MOF composites materials composed of MOF and more distinct constituent materials，including other MOFs，with properties noticeably different from those of the individual components．In composites，the advantages of both MOFs(structural adaptivity and flexibility,high porosity with ordered crystalline pores)and various kinds of active materials(unique optical，electrical，magnetic and catalytic properties)carl be combined effectively,and therefore，new physical and chemical properties and enhanced performance that not attainablebytheindividualcomponentsmaybeaccessed．Theremarkablenewpropertiesandmultifunctional nature of the emerging MOF composite materials will stimulate the emergence of innovative industrial applications in diverse range of technologically important fields．These MOF composites may be used directly innovative advanced materials precursors of novel inorganic solids，providing promising applications in fimctional and protective coatings，storage and separation,heterogeneous catalysis，sensing， biology and medicine．On the other hand，MOFs with large surface areas，adjustable pore sizes and incorporated redox metal centers becoming new type ofpromising electrode materials in SCs．To allow fast diffusion of active ions during charging／discharging process，pristine MOFs with tailored pores channels III 万方数据 万方数据 万方数据 desirable for applied in SCs．The non-conductive