两种碱复合预处理对玉米秸秆厌氧消化产气性能的影响研究环境科学与工程专业论文.docxVIP

北京化工大学硕士学位论文越好。 北京化工大学硕士学位论文 越好。 在单独碱液预处理的基础上，为了节约预处理成本，研究了不同配比 的KOH和Ca(OH)2常温联合预处理对玉米秸秆厌氧消化产气性能的影响。 结果显示，KOH和Ca(OH)2常温联合预处理能有效提升玉米秸秆的产气 性能，在保证厌氧消化效果的前提下可用Ca(OH)2部分替代KOH，减少 KOH的用量。从节约成本的角度考虑，可选用o．5％KOH与2．o％Ca(OH)2 混合预处理工艺，其累积甲烷产量与2．O％KOH单独预处理没有显著性差 异，为271．4 mL·gvs1，比未预处理提高了77．O％。 此外，本课题还研究了热碱预处理对玉米秸秆厌氧消化性能的影响。 在55C下，分别采用不同浓度(0．5％、1．5％、2．0％、2．5％，w／v)KOH、 Ca(OH)2以及不同配比的KOH和Ca(OH)2联合方式对玉米秸秆进行预处 理，考察预处理温度提升后对厌氧产气效果的影响。结果显示，单独碱的 热预处理能显著提升玉米秸秆厌氧消化产气性能。2．0％KOH预处理条件 下产气性能最好，厌氧消化累积甲烷产量达到最大值290．8 mL·gvs～，比 未预处理秸秆提高了86．6％。热Ca(OH)2预处理比常温Ca(OH)2效果有显 著提升，1．5％Ca(OH)2预处理累积甲烷产量为242．2 mL·gvs～，比常温的 同浓度条件下产甲烷量提升了19．7％，而热碱联合预处理的替代效果却不 如常温碱联合预处理。因此从成本节约的角度考虑，55C下，1．5％Ca(OH)2 预处理为最适宜的条件。 关键词：玉米秸秆，厌氧消化，氢氧化钾，氢氧化钙 Ⅱ 万方数据 ABSTRACTRESEARCH ABSTRACT RESEARCH ON ANAERoBIC DIGESTION OF CORN SToVER BY TWO KINDS oF ALKALI PRETREATMENTS ABSTRACT Corn stover is an abundant biomass and inevitable co-product of corn grain product in China．With the characteristics of distributed dispersion， lower bulk density,seasonal and higher transportation costs，a large amount of com stover has not been effectively used and abandoned as solid waste and even burnt in the open field directly,which is causing severe environmental problems．Anaerobic digestion has proven to be an environment-friendly technology to convex com stover to clean biogas to achieve its resource utilization．Theoretical methane yield of com stover was calculated to be 43 1．2 mL·gvs～according to the elements analysis results．Corn stover with complex lignocellulosic structure，it is necessary to do some pretreatment work to break the connection between 1ignhl and cellulose components in order to increase the hydrolysis speed in the process of anaerobic fermentation and improve the biogas conversion efficiency．In this study,the effects of potassium hydroxide and calcium hydroxide pretreatment on the performance of anaerobic digestion and influence on the com stover structure were studied． Firstly,select KOH and Ca(OI-I)2 as pretreatment reage