乙烯环氧化反应器飞温致灾机理及预防研究机械工程专业论文.docxVIP

北京化工大学硕士学位论文和生产运行效率，确定了各参数的操作敏感区域和适宜操作范围。分析结 北京化工大学硕士学位论文 和生产运行效率，确定了各参数的操作敏感区域和适宜操作范围。分析结 果认为：较高的乙烯浓度、氧气浓度、进料流量、进料温度、汽包温度、 操作压力和较小的孔隙率对床层温度和反应速率具有提升作用；其中乙烯 浓度、氧气浓度、汽包温度和孔隙率对飞温事故发生具有重要影响，是需 要重点监控的操作参数；进料流量、进料温度和操作压力对飞温事故发生 的影响作用有限。 (3)以HAZOP分析中的节点单元、设备及偏差为对象，依据HAZOP 风险分析结果和参数波动影响研究，结合装置工艺安全资料分类管理，构 建了乙烯环氧化反应器飞温事故预防信息指导系统。监控、预测并分析参 数波动可能出现的异常工况和后果，实现工艺技术资料快速定位和查阅， 辅助应急决策，为预防反应器飞温事故的发生提供信息指导。 本文依据乙烯环氧化反应器风险分析、参数波动影响模拟和工艺安全 管理，研究反应器飞温事故发生原因，构建事故预防信息指导系统，为反 应器飞温事故预测、预警和保障设备安全高效运行提供技术依据。 关键词：乙烯环氧化反应器，飞温，HAZOP分析，FLUENT，参数敏感 性，工艺安全管理 万方数据 ABSTRACTSTUDY ABSTRACT STUDY oN CAUSING MECHANISM AND PREVENTIoN oF THE TEMPARATURE RUNA、)l馅LY ACCIDENT FOR ETHLENE EPoXIDATIoN REACToR ABSTRACT In the ethylene oxide／ethylene glycol plant，ethylene epoxidation reactor is an important equipment of the oxidation reaction part．Because of extreme operating environment such as high temperature and high pressure as well as complex coupling effects of potential risk factors，the reactor tends to be operated in abnormal condition，and the temperature may runaway,SO that when the parameters change，it may be followed by serious accidents．In order to study the mechanism of reactor temperature runaway and prevent accidents， this paper has identified the potential risks，analyzed the operation parameters which influenced the reaction running states by using Hazard and Operability Analysis(HAZOP)method．Then the working process in the reactor is simulated by using FLUENT software to monitor the distribution of components and temperature dynamically．Based on those simulation results， the influence of operation parameters fluctuation on the heat balance and operation effect in the reactor are analyzed，and mechanism of temperature runaway leading to accidents has been proposed．Finally,according to risk analysis results，influences of parameter fluctuations and process safety management，this paper builds an information guidance system to prevent temperature runaway accidents，and provide technical basis for prev