bn负载贵金属催化肉桂醛选择性加氢反应研究化学工程与技术专业论文.docxVIP

广东工业大学硕士学位论文Abstract 广东工业大学硕士学位论文 Abstract Cinnamaldehyde(CAL)is one of the typical representative a，13-unsaturated aldehydes， which Call be hydrogenated to cinnamyl alcohol(COL)，a widely used chemical in perfume and pharmaceutical industry,or hydrocinnamaldehyde(HEAL)，an important intermediate of anti-HIV drug．Further hydrogenation of COL and HCAL leads to the formation of 3-phenyl． 1-propanol(PPL)．Although the hydrogenation of C=C is thermodynamically favorable than that of C=0 group，the mixture of various products is generally obtmned in CAL hydrogenation and the mechanism of selecvitity is not clear SO far．Therefore，designing the efficient catalyst is of great scientific importance and also of industrial interest for highly selective hydrogenation of cinnamaldehyde． The hexagonal boron nitride(1l-BN)，also called white graphite,is one of the promising inorganic material with excellent physical and chemical properties．In this thesis，h-BN was used to support Pt and Rh，highly effective metals for catalytic hydrogenation，and the resulting supported catalysts were tested in liquid phase cinnamaldehyde hydrogenation at room temperature．The influence of various noble metals，carriers and reduction conditions on the hydrogenation performance were studied，the reaction conditions such as solvent，temperature． pressure and time were optimized，and the reaction kinetics were investigated as well．The main results are as follows： 1．Selective hydrogenation of CAL was studied in the liquid phase over various noble metals supported on h-BN．Pt／BN performed a desired selectivity to COL with higher activity， while Pd and Rh showed higher selectivity hydrogenation for C=C and little for C=O，and the performance of Ru Was in between．et(NH3)4·(N03)2 was selected as Pt precursor to prepare the supported catalysts．PffBN performed highest selectivity for cinnamyl alcohol than A1203， si02 and graphite supported Pt catalysts．1 wt．％Pt／BN exhibits CAL conversion of 95．8％ and a selectivity of 85．2