pphtms新型优先透醇膜的制备及改性研究化学工程与技术专业论文.docxVIP

北京化工大学硕士学位论文为79、HSO用量为1．59，催化剂用量为0．29，溶剂用量为109时，分离 北京化工大学硕士学位论文 为79、HSO用量为1．59，催化剂用量为0．29，溶剂用量为109时，分离 35℃的9wt％的乙醇／水溶液，分离因子为5左右，渗透通量为 4404．449·m-2·h～。当料液温度为35℃时，随着乙醇浓度的升高， PPhTMS．HSO膜的分离因子逐渐下降，渗透通量逐渐升高：当乙醇浓度 为9wt％时，随着料液温度的升高，PPhTMS．HSO膜的渗透通量逐渐升高， 分离因子先升高后降低，在35℃时膜的分离因子达到最高值。 关键词：PPhTMS，PPhTMS-X，乙醇／水，渗透汽化 Ⅱ 万方数据 ABSTRACTPREPAR ABSTRACT PREPAR ATION AND MODIFICATION oF PPHTMS NoVEL ETHANoL．PERMSELECTIVE MEMBRANE ABSTRACT Ethanol fermentation is a typical product inhibition process，the combination of pervaporation and biological fermentation can successfully in situ separate ethanol from fermented liquid，reducing the inhibition of yeast fermentation．It is important to select a suitable membrane material in pervaporation process．As traditional commercial membrane，PDMS has high separation factor．However,the low permeation of flux impedes its industrialization．Thus，the preparation of a membrane with both high separation factor and high flux remains a hot research direction． In this research，a novel Poly(Phenyltrimethoxysilane)(PPhTMS) membrane had been developed．In order to improve its pervaporation performance，flexible segments HSO and PDMS were used to modify PPhTMS membrane，which could form soft-hard intersection structure and lead to the formation of a novel PPhTMS·-X ethanol·-permselective composite membrane．After the flexible segments were introduced，the changes of surface structure and chemical properties of PPhTMS membrane are HI 万方数据 万方数据 万方数据 北京化工大学硕士学位论文analy’sised 北京化工大学硕士学位论文 analy’sised through the following characterization methods：scanning electron microscopy(SEM)，atomic force microscope(AFM)，contact Angle test(CA) and SO on．It was found that PPhTMS—HSO membrane has a better seperation performance through inspecting the effects of additive amount and membrane--forming temperature on PPhTMS··X membrane pervaporation performance．Besides，the effects of solvent amount，catalyst amount，feed concentration and feed temperature on PPhTMS-HSO mem