亲水性有机硅织物柔软剂的合成和性能研究化学工程专业论文.docxVIP

广东工业大学硕士学位论文综合对比，我们发现7000分子量的双端环氧聚硅氧烷与M2070合成的20％梳状结构 广东工业大学硕士学位论文 综合对比，我们发现7000分子量的双端环氧聚硅氧烷与M2070合成的20％梳状结构 的梳状聚醚氨基改性聚硅氧烷，具有良好的亲水性和优异的柔软性，综合性能最佳。 通过与市售产品对比，我们的产品亲水性能达到4．10s，柔软性4．6分，白度为 73．9‰虽然在亲水性上并未达到极致，但柔软性突出，抗黄变性能优异，就综合性 能而言我们的产品已经达到了较高的水准，具有很大的应用价值。 关键词：梳状；聚醚；氨基硅油；合成；亲水性；柔软性 万方数据 AbstractSilicone Abstract Silicone softening agent is the most widely used textile finishing agent in the market, which is called super softening agent because of its excellent softness，smoothness and film formation．But，amino-silicone oil is not perfect,its low hydrophilic，easy to yellow has also greatly restricted its development．Hydrophilicity and flexibility is a pair of contradiction， silicone softening agent has experienced several generations of development is still difficult to take into account．In this paper,in consideration ofthe soft and hydrophilic property for the purpose of synthesized a new type of hydrophilic silicone softener：comb amino polyether modified polysiloxane，it Can make hydrophilic softness and achieve a higher level ofbalance， but also can effectively resist yellowing．The specific research contents and conclusions are as follows： (1)Terminated—hydrogen polysiloxane and allyl glycerin ether as starting materials synthetize terminated-epoxy polysiloxane under the action of Speier catalyst．Then through single factor method optimize reaction conditions．Finding the optimum reaction conditions： material ratio n(terminated-hydrogen polysiloxane)：n(allyl glycerin ether)2 l：1．2．2％Speier catalyst’S dosage is 20ppm，the reaction temperature is 85℃，reaction time is 5h．After optimization，the highest conversion rate of the product Was 89．5％，and the epoxy value was 0．02796％．Through IR and H NMR analysis show that the product of silicon hydrogen addition reaction completely,not containing Si—H bond，on both ends ofthe polysiloxane chain is connected to the epoxy group，synthesis of the required product structure． (2)Terminated-epoxy polysiloxane synthetized by the first step a