超临界流体制备超微粉体装置设计与结晶器流场模拟化工过程机械专业论文.docxVIP

摘要摘要 摘要 摘要 本文首先介绍了超临界流体(supercritical fluid，SCF)fl引J备超微颗粒技术的几种 工艺技术，并对目前应用较广泛的SAS与RESS工艺过程的装置研究概况进行了 综述。进行改进与优化装置设计工作，可促进该项技术的规模化生产与应用。 设计了两种新型工艺流程，即连续型SAS／RESS通用和小型SAS／RESS通用 流程，并对前者的操作过程及特点进行了介绍。对该流程的关键设备溶解釜、结 晶器、喷嘴等进行了结构设计，确定了他们的主要尺寸、安装方式，对其功能作 了详细说明。 结晶器作为工艺流程的关键设备，是粒子生成的主要场所，SCF和溶液在这 一结晶区混合效果的优劣直接影响着产生粒子的直径及其分布范围。因此，根据 计算流体动力学的理论分析方法，以两通道外混结晶器组件为例，建立了结晶区 的几何模型，利用Gambit软件，划分了网格，然后将其导入Fluent软件进行了模 拟计算，分析了温度计套管、结晶器形状等因素对结晶区混合效果的影响。得出 当温度计套管接近于喷嘴喷出区域时，对结晶器流场的影响较大，而结晶器与喷 嘴结合部的直角区域的存在会导致湍流程度的增大。据此对结晶器的结构及温度 计套管的位置进行了重新修正，有效地改进了SCF和溶液的混合效果，对结晶器 的改进设计与加工制造具有指导意义，对SCF制备微粒技术尽早用于工业化生产 起到了良好的推动作用。 关键词超临界流体；结晶器；数值模拟；流场分析 V¨ 山东人学硕+学何论文Abstract 山东人学硕+学何论文 Abstract In this paper the technology of preparing superfine particles using supercritical fluid(SCF)technology has been introduced first，the summarization of SAS and RESS equipment has also been given．By improving and optimizing the equipment design，the SCF technology could be used more widely in industry． Two new flowcharts，which are the continuous versatile process and the experimental versatile process，were designed．The operating specification and the specialties of the continu．3US versatile process have also been determined．The specific operating condition and the capability of the equipment were introduced for the experimental versatile process．The structures for the main parts，such as the dissolving vessel，the precipitator and the nozzle，were designed in this paper,and their dimension and installation specification were given，the specification of their capability Was presented as well． The precipitator is the most important part for the technology,which is the location of preparing particles．The SCF and the solution get mixed in this vessel，and their mixing effect has a great influence to the final size and the distribution of the particles． We selected the model of two-passages with blend-outside mode precipitator as a simulating example．Based on the numerical analysis of Computational Fluid Dynamics (CFD)，the geomet