磁场诱导钴纳米粒子一维组装与生长材料物理与化学专业论文.docxVIP

ABSTRACTDriven ABSTRACT Driven b)r the promising applieatiom in laigh-demity magnetic data storage media, ferrofluids，arid biomedicine，a significant researela effort has been put in the s3mthesis of nanoseale magnetic materials．MoleOVCl,ordered ftmetional struetttres of magnetic nanomaterials have S0111e brand-new properties resulted from the spatial orientation and arrangement of the building blocks and can be viewed弱the foundation for the formation of novel miniaturized nanodeviees．So research on the assembly of nanoseale magnetic materials is very important from tlae point of view of science and applications． The objective of this dissertation is to explore new a：、Ieilllc for the solution-based synthesis of nanoseale magnetic materials under magnetic fields，investigate the relationship between their magnetic parameters arid their structure(size and／or shape)，and develop S0111e simple and effective technologies for assembling the magnetic block buildings into highly ordered fuaetioml$1ructurcs．The main parts of the results ale summarized below： 1．Two kinds of cobalt mnoehaim with different particle size and interspace WaS successfully synthesized tmder extcnlal magnetic field．We find that cobalt nanopartieles within each chaill can spontaneously assemble into 011c dimensional structure along the magnetic force line．The mechanism of chain formation is discussed舔follow．Firstly，cobalt mnopartieles wcrc produced in the rcactioll system；secondly，the newly formed particles assemble into 011e dimensional chains under external magnetic field．There a聆various experimental parameters responsible for tlae formation of ehaim．For ilIst狃ce，the amount of P、，P and the speed of both titration and stirring can significantly affect the size of particles and their i-terspaee．Only particles with appropriate size and nalTOW size dislribution can assemble into I,erf鳅chaill structure．Or,the other hand,the magnetization time of 0111sample弱well as the strength of the external magnetic fi