对不同乳化方法合成的水性聚氨酯后扩链的研究应用化学专业论文.docxVIP

AbstractAbs仃act Abstract Abs仃act In this paper，the main research is the tIlree dif琵rent types of emuIsi矽ing method of expandiIlg chain：generaI method of enmlsi蛳ng chaill extension，s”chronous chain extension emulsi6cation method and reVerse chain extension memod．Change me temperamre iIl me process of post．cha证extension and t11e content of DMI，A in t11e process of compound访g the pr印olymers to compound a series of wate加me polyurethane．And men use a more accurate method to deternline the subsequent chain eXtension efnciency． Residual amino can be measured by reactiIlg with nirlllydr访、Ⅳhich caJl make锄iIlo color．The basement of the absorption peaks caJl be measured by UV-Vis． Then the innuence of山e particle s泣e and post-cha．m temperature on the chain e)(tension emciency can be discussed． (1)In the post—chain e)(tenSion process usmg t11e general method of expanding chain to compound wate渤me polyurethaIle under di脏rent temperal=ure and di脏rent content of DMPA． The ma．m research on t11e process of也e synthesis of wate批me polyurethane， the residual NH2 changes with me temperature changing，t11e particle s讫e changes and the residual NH2 changes with the panicle s讫e changiIlg．Then t11e sample emulsions react with ninhyd血，uIlder t11e uV-Visible spectm，measure the ultraViolet-Visible abso印t．on peaks．At the s锄e tinle，we also me2Lsure the particle s娩e，iIl仔ared detection，and solid content． This chapter studies show that：when add the s锄e content of DMI，A at thc difrerent tempera：cure，the cham extension emciency is high at 20℃，30℃and 40℃， low at high temperature aJld low tempemture．Research on me reaction condition of the s锄e content of DⅣⅢA and difrerent temperamre，we f-md t11at with the temperature changiIlg，the particle s泣e changes irregular．Research on the reaCtion condition of me same tenlpemture and difrerent content of DMPA，we f．md that with the content of DⅣmA rising，the particle s娩e rises．Research on the relationship of t11e residual NH2 groups and the particle s泣e，we find th