大孔n甲基咪唑阴离子交换树脂的制备及其对crⅵ吸附性能的研究应用化学专业论文.docxVIP

关键词：大孔树脂；离子交换；N．甲基咪唑；Cr(VI) 关键词：大孔树脂；离子交换；N．甲基咪唑；Cr(VI) 万方数据 SYNTHESIS SYNTHESIS OF MACRoPoRoUS N．METHYLIMIDAZoLIUM FUNCTIoNALIZED ANIoN EXCHANGE RESINS FOR ADSORPTION OF Cr(VI) ABSTRACT Heavy metal chromium is very harmful to human health and it is urgently to solve the problems of chromium pollution．Ion exchange resin is a kind of network structured polymer compound which can realize the processes of adsorption， seperation and purity based on the carried functional groups with the ion exchange． Ion exchange resins are widely used various areas such as hydrometallurgy, wastewater treatment and SO on． In this thesis，aiming to remove Cr(VI)from aqueous solution， N—methyimidazole functionalized macro porous anion exchange resins(PCI and P2S04)were prepared by anchoring N—methyimidazole on macro porous ch010romethylated copolymer of styrene—divinylbenzen(PS-DVB)．It was shown that the prepared anion exchangers exhibited high thermal and chemical stabilities．The decompositon starting temperatures of PCI and P2804 are 226。C and 2 1 5。C respectively．PCI and P2S04 resins also had good stability in acidic and basic degration agents．Moreover,on the basis of formulation of N‘methyimidazole 万方数据 functionalized functionalized macro porous anion exchange resins prepared in the laboratory,the scale—up experiment was conducted in the pilot plant．The problem of engineering amplification was initially solved．The ratio of reactants and the process conditions were optimized．The contract requirment was met by the pilot test products and the yield ofPCI is 91．54—94．1％． For the remove of Cr(VI)from aqueous solution，the results of static adsorption test indicated that the N-methyimidazole functionalized macro porous anion exchange resins PCI and P2504 exhibited high adsorption efficiency and selectivity． The adsorption process is exothermic．The maximum Cr(VI)adsorption capacities are 1 88．4 mg／g and 1 57．8mg／g for PCI and P2504 respectively．The fixed bad column model results exhibi