改性活性炭的制备及其吸附微污染水源水中ni2的研究环境科学与工程专业论文.docxVIP

广东工业大学硕士学位论文方程，对Ni2+的吸附过程更符合准二级动力学方程，改性前后活性炭对Ni2+吸附符合 广东工业大学硕士学位论文 方程，对Ni2+的吸附过程更符合准二级动力学方程，改性前后活性炭对Ni2+吸附符合 单分子层吸附的特点，吸附过程以化学吸附为主，由外扩散和内扩散过程共同控制。 三种活性炭经过改性后对微污染水源水中的Ni2+均有较好的去除效果，为微污染 水源水中Ni2+的去除提供参考。 关键词：改性活性炭；微污染水源水；镍；吸附 万方数据 ABSTRACTABSTRACT ABSTRACT ABSTRACT There is a growing concern about drinking water safety due to the severe water pollution problem and increasingly stringent water quality standards．The incidents of heavy metal pollution unexpected have serious impact on the operation of water supply plant．More attentions have been paid to the nickel due to its carcinogenic and contamination accidents． Active carbon adsorption is of great advantages in simple process and renewable，SO it is widely used for removal of Ni2+from water．However,the adsorption performance of general activated carbon for Ni2+is pool it is necessary to change the physical and chemical properties of activated carbon by modification for improving its adsorption propenles· In this paper,the Ni2+in slightly．polluted source water was studied and the activated carbon was used to adsorb Ni2+due to its safety and non-toxic．The coconut shell activated carbon(CS．AC)，the wood activated carbon(W-AC)and the coal activated carbon(C-AC) were modified and the best modification solutions were determined by orthogonal experiments．The surface characteristics of the activated carbon before and after modification were analyzed by Scanning electron microscope，N2 Brunauer-Emmett-Teller adsorption aIlalysis， Fourier transform infrared spectrometry and Boehm titration·The influence of activated carbon dosage，reaction time，pH value and initial concentration on the adsorption of Ni2+were explored．The adsorption properties of activated carbon before and afler modification for Ni2+in slightly．polluted source water were compared．In addition，the mechanism of adsorption of Ni2+Was studied preliminarily through adsorption thermodynamics and kinetics． The results showed that： (1)The CS．AC was modified by HN03．KO