臭氧催化氧化和活性炭吸附在化工园区难降解污水深度处理中的试验研究化学工程专业论文.docxVIP

北京化工大学硕=l二学位论文改性活性炭和椰壳活性炭的最佳活性炭投加量同为29／L，二者最佳的 北京化工大学硕=l二学位论文 改性活性炭和椰壳活性炭的最佳活性炭投加量同为29／L，二者最佳的 吸附时间都是30min。升温于促进活性炭吸附速率，但对最终的吸附 平衡点影响较小。此外，通过对试验数据进行动力学分析发现活性炭 吸附过程中液膜扩散是主要控速步骤。通过对试验数据进行热力学分 析发现活性炭吸附主要为物理吸附，更加深入的了解活性炭吸附机 理。 在臭氧催化氧化工艺和活性炭吸附工艺分别作用的研究基础上， 试验综合利用了臭氧催化氧化工艺和活性炭吸附工艺对试验污水进 行了处理。试验发现，臭氧催化氧化工艺和活性炭吸附工艺的组合工 艺对污水的处理效果较单独使用臭氧催化氧化工艺或活性炭吸附工 艺有明显的优越性。试验对比了AC+03工艺和03+AC工艺研究发 现，二者均可以达到试验出水COD小于50mg／L的国家排放标准且 AC+03工艺具有一定经济性。试验创新性的将活性炭吸附工艺和臭氧 催化氧化工艺组合到了一起，化工园区难降解污水的COD去除率最 高可达到82％。 关键词：臭氧催化氧化，活性炭吸附，难降解废水，化工园区，催化 剂 万方数据 ABSI’RACTC夕姐、ALYTIC ABSI’RACT C夕姐、ALYTIC OXIDATION OF OZONE AND ACTIVATED CARB ON AD SORPTION PROCE S S DEEPLY TREATING REFRACTORYⅥ7：f～STEⅥ馅LTER FROM CHEMICAL INDUSTRIAL PARK ABSTRACT The sewage water which comes from sewage treatment plant in chemical industrial park is complex，difficult to be degraded．The sewage water which used by the test water come from jiangsu yancheng a sewage treatment plant．Ozone catalytic oxidation process and activated carbon adsorption process are used to deep treat the refractory wastewater which comes from the sewage treatment plant．At the same time，explore the ()zone catalytic oxidation process and activated carbon adsorption process conditions，and the effects of factors on processing conditions，and seeking the optimal process conditions for ozone catalytic oxidation process and activated carbon adsorption process．And innovative to ozone catalytic oxidation process and activated carbon adsorption process together．Find a new treatment method to treat the refractory wastewater froln the chemical industry park．In consideration of economy and under the condition of treatment effect，make the refractory wastewater reaches the national emission standards． 万方数据 万方数据 万方数据 北京化丁大学硕上学位论文Article 北京化丁大学硕上学位论文 Article separately study ozone catalytic oxidation process and activated carbon adsorption process，and the effects of reaction conditions on the process．The categories of catalyst which used in ozone catalytic oxidation process are s