分子氧环氧化烯烃多相催化剂的研究物理化学专业论文.docxVIP

不对称的方式被活化。 不对称的方式被活化。 关键词：烯烃，环氧化，氧气，多相催化，环境友好 ll AbstractMany Abstract Many researchers used alkyl hydroperoxide，hydrogenperoxide and molecular oxygen (oxygen air)as oxidant for aikene epoxidation．Alkyl hydroperoxide is a good oxidant for alkene epoxidation，but it is expensive．Molecular oxygen is the most ideal oxidant between the three，because it is cheap and green．Hydrogenperoxide is also a cheap and environment-friendly oxidant，but it is expensive and hard for storage compared with molecular oxygen． Hydroperoxide will bring CO-product—water when using it as oxidant，but not for molecular oxygen under the condition of no sacrificial reductant．Therefor,epoxidation of styrene， cyclohexene，propene and butene with molecular oxygen(oxygen or air)over heterogeneous catalyst was investigated in this paper．Alkene epoxidations under various catalytic system over different catalyst synthesized in the paper based on different aikenes were researched． Concretely,the following content were researched in this paper： (1)Co／TS·1 synthesized by impregnating method was applied in styrene epoxidation． Styrene epoxidation by oxygen using N．N-dimethylformamide(DMF)嬲solvent was ca盯ied out under the condition of 1 00℃and atmospheric pressure．In the experiment，oxgen was added into the system by bubbling．The effects of cobalt amount in the catalyst，calcination temperature of the catalyst，supports of the catalyst,reaction temperature and flow rate of oxygen on the catalytic results were investigated．94．5％styrene conversion with 74．3％ epoxide selectivity was obtained under the optimal conditions．The stability of the catalyst was tested．The catalyst was used consecutively for 5 times without significant styrene conversion and epoxide selectivity change．In addition，the mechanism of the catalytic reaction was explored and the reaction follows the free·radical mechanism． (2)Two different metal Schiff-base composite catalysts with montmorillonite as support (Co·mont(Lx)and Mn-mont(Lx))were synth