多壁碳纳米管的超声处理对PtRuMWCNTs电催化性能的影响.PDFVIP

PtRu/ MW CNTs 79 PtRu/ MWCNTs Study of Functionalization on M ult-i wall Carbon Nanotubes by U ltrasound 1 1 2 1 , , , ( 1 , 150001; 2 , 1000 1) 1 1 2 1 YAN G Chun-w ei , HU Xin-guo , ZHANG Liang , DAI Chang-song ( 1 Department of Applied Chemistry, Harbin Institute of T echnology , H arbin 150001, China; 2 Department of M aterial, Beijing Institute of Technology, Beijing 1000 1, China) : , , , , , , , PtRu : ; ; ; : TM 9114 : A : 1001-43 1( 200 ) 07-0079-04 Abstract : Functionalization of multi-wall carbon nanotubes ( MWCNT s) was important for application in catalytic realm. MWCNT w as purified during the sonochemical treatment w ith nitric and sulfuric acids. At the same time, MWCNT w as shortened and its ports w ere opened. MWCNT w as also deco- rated by a great lot of oxygen-contained function groups on the surface and ports. It w as good for the active elements to deposit on the surface uniformly. T ransmission Electron M icroscope ( TEM) , Ra- man spectrum, Infrared spectrum ( IR) w as used to characterize the degree of surface functionalization and coverage. T he PtRu catalyst w hich w as supported w ith treated MWCNT w as also studied in the w ay of Cyclic Voltammetry( CV ) and Electrochemical Impedance Spectroscopy( EIS) , and a better methanol electrooxidization activity w as gained. Key words: MWCNT s; sonochemical treatment; functionalization; Raman spectrum; DMFCs [ 1] 1991 Iijima , ,