冲击波作用下纳米tio2粉体的烧结性能研究材料学专业论文.docxVIP

西南科技大学硕士研究生学位论文 西南科技大学硕士研究生学位论文 第1页 摘 要 本文利用冲击波技术对商品锐钛矿相纳米Ti02粉体进行冲击实验。研 究了装置参数、装样量和装药量对纳米Ti02粉体性能的影响。研究结果表 明：平面冲击波加载回收装置实现了样品的完整回收。冲击后粉体的衍射 峰强度下降，冲击波作用有效的抑制了晶粒的异常长大。在高炸药量的冲 击下，产生大量的晶格畸变，晶型呈现无序化。 将冲击后的粉体进行后续烧结，随着炸药量的增加和冲击压力的增大， 颗粒间储存了更多的由于晶格畸变和微观缺陷形成的能量，这部分能量在 后续烧结过程中得以释放，使样品的相变温度呈现下降的趋势。高炸药量 冲击作用的粉体，在后续烧结过程中，粉体的粒径小，均匀性较好。与常 规烧结相比，冲击作用可以使晶粒细化、均化和抑制晶粒异常长大。在后 续烧结中的高温作用下，高炸药量作用下样品的晶粒生长快，晶粒间的空 隙增多，但不如低炸药量冲击后粉体烧结的致密度好。 通过对冲击波作用下纳米Ti02粉体的微观结构变化规律和其烧结性 能的研究，拓宽了冲击波技术在材料科学中的应用领域，并且为纳米陶瓷 烧结的新途径提供了理论和数据支撑。 关键词：Ti02 冲击波 纳米 烧结 相变 Abstr Abstr acl： In this paper,commercial anatase nano titanium powders were impacted by shock wave technique．The affect of device parameters，sample loading capacity and loading dose on the properties of nano titanium powders were investigated．The results showed that the samples were recovered completely by planar shock wave loading recovery device．X diffraction intensity of the powders decreased and the abnormal growth of grains were inhibited effectively under the action of the shock wave．In the case of a large quantity of high explosives，the crystal present disorder and a large number of lattice distortion were produced under the impact action． The powders after impacted were sintered．With the high explosives， more energy engendered by the more lattice distortion and defects was stored among the particles．This energy can be released during subsequent sintering， which caused the phase transition temperature of the sample showing a downward trend．In the subsequent sintering process，particle size of the powders impacted by the shock wave was small and uniformity．Compared with conventional sintering，shock wave technique could make fine grain and restraint all abnormal grain growth．Under the high temperature of the follow．up sintering，the size of the sample impacted by the high explosives and space between the grains rapidly increased，but the consistency was worse than the powders impacted by the lower explosives． Because the microstructure and sinterin