碳气凝胶的结构重整及其电化学行为-IngentaConnect.PDF

物理化学学报(Wuli Huaxue Xuebao) February Acta Phys. -Chim. Sin . 2012, 28 (2), 361-366 361 [Article] doi: 10.3866/PKU.WHXB201112063 碳气凝胶的结构重整及其电化学行为 徐子颉* 吉 涛 赵 蕾 王玮衍 杨春艳 甘礼华 ( 同济大学化学系, 上海200092) 摘要: 将碳气凝胶(CAs)在金属钠熔体中于800 °C 加热3 h, 制得结构重整的碳气凝胶(RCAs), 并研究了它们 的电化学行为. 采用X 射线粉末衍射(XRD)、激光散射拉曼(Raman)光谱、气体的吸附与脱附(BET 法)、透射电子 显微镜(TEM)以及电化学阻抗谱(EIS)等手段, 对CAs 和RCAs样品分别进行了表征. 结果表明: 无定形态的碳单 质微粒在金属钠作用下发生结构重排; 所得RCAs 的比表面积比CAs 的大约增加48%; RCAs 中孔径在2 和4 nm 尺寸处, 呈现比较集中的分布, 孔径小于10 nm 以下的孔体积占其总孔容的30%, 是CAs 的3 倍. CAs 和 RCAs样品的电化学测试结果表明: RCAs 内部接触电阻约为CAs 的45%, 并保持了明显的电容特性. 关键词: 碳气凝胶; 金属钠熔体; 结构重整; 电化学阻抗谱 中图分类号: O646; O642; O792 Restructured Carbon Aerogels and Their Electrochemical Performances XU Zi-Jie* JI Tao ZHAO Lei WANG Wei-Yan YANG Chun-Yan GAN Li-Hua (Department of Chemistry, Tongji University, Shanghai 200092, P. R. China) Abstract: Restructured carbon aerogels (RCAs) were obtained by annealing carbon aerogels (CAs) in sodium melt at 800 °C for 3 h and the differences in electrochemical performance between the resultant CAs and RCAs were studied. X-ray diffraction (XRD), Raman scattering spectra, gas physisorption (BET), transmission electron microscopy (TEM), and electrochemical impedance spectroscopy (EIS) were used to probe the structures of CAs and RCAs. The studies indicated that the amorphous carbon particles were rearranged in sodium melt, in which the surface area of the resultant RCAs was 48% larger than that of CAs. Two concentrated pore distributions were observed at the apertures of 2 and