溶凝胶过程与温度之关系xerogelfilmheatdensefilmdenseceramics.PPT

The structural groups of alkali silicate glasses determined from 29Si MAS-NMR (Journal of Non-Crystalline Solids 127 (1991) 53-64) 29Si MAS-NMR spectra of sodium silicate glasses. 29SI MAS-NMR spectrum of sodium metasilicate glass. Experimentally determined Q, distribution in lithium (△), sodium (□) and potassium (○) silicate glasses as a function of moll% of alkali oxide. Fitted lines were calculated from equilibrium constants shown in table. , Q4; , Q3; , Q2； , Q1, , Q0. Conclusion: The detailed distribution of the structural units Qn in binary silicate glasses was determined by means of the MAS-NMR technique. The equilibrium of the following types were found apparently to govern the concentrations of Qn species, 2Qn Qn-1 + Qn+1 (n = 3, 2, 1), of n = 3, 2, 1 for sodium and potassium and n = 3, 2 for lithium silicate glasses in limited composition ranges. The agreements with the thermodynamic data were quantitative in the sodium and potassium silicates but only qualitative in the lithium silicate. The chemical shift for all Qn, species depends linearly on the composition and the slopes are less for Qn, with smaller n. The linear relations between the averaged chemical shift and the theoretical optical basicity strongly suggest the potential use of the 29Si chemical shift as a scale for the basicity of the system. Structure of sodium aluminoborate glasses study by NMR (Solid State Nuclear Magnetic Resonance 27 (2005) 37–49) 27Al B=18.8T 11B B=14.1T 17O B=14.1T Random mixing model: In a random mixing model without any constraints. 4–4 avoidance model: In this model, connections between tetrahedral network units, [4]M–[4]N (avoidance of [4]Al–O–[4]Al, [4]Al–O–[4]B and [4]B–O–[4]B species) are unfavorable, involving only trivalent cations (B and Al). oxygen containing [5,6]Al three-coordinated Con