带配位基自由基金属配合物的设计合成结构和磁性研究无机化学专业论文.docxVIP

南舞走拳薅击学往论文 南舞走拳薅击学往论文 援要 s40568 摘 要 论文围绕带配位基自[；扫基一金属配合物这一分子磁体的热点领域，合成了六 令带酝蕴蘩匏氦鬣鑫壶基懿蒋，弱用这骜配诲设计合残了28令黩鬏豹i熏渡金属 配合物，黛部解析了这些配合物的晶体结构。应用元素分析、红外光谱、电子光 谱、X-=鸯孛线衍射、糇磁共振、交滠磁亿率戮及变蛹磁纯率等手段对部分§0合物避 行了表征鄹性质研究。 利用桥联配体组装了五个一维链状自由基配合物。运黼近似磁学模鹜评估了 磁糖互作用的大小。首次合成了壮1．1叠氮双挢联接的铁磁性C001)一自由基配合 物，利用蹙温、变场磁化率及Brillouin酗数等评估了该配合物中存在的铁磁相 要稼翅。蔫次合成巍骚究了挠磁衾疆AS(D离予联接熬一维塞由鏊链磁憋链状配 合物。探讨了抗磁金属在磁交换中的作用，为研究抗磁金属离子传递氮氧自由基 阗磁褶互话蘑耄}{I遴提供了实验裱攒。对帮分鑫由潦配合貔送行了蓬纯诗冀，为疆 究配合物中自由熬与金属间的磁交换作用提供了～定的联论依据。 关键词：氮氧自融基，配食物，熬蒋结{勾，磁性，量化计算 南开大学博士学位论文 南开大学博士学位论文 摘要 Abstract The design and synthesis of complexes of metal radical with coordinating group is one of the most attractive field in the molecular-based magnetic materials．In order to investigate the correlation between the structure and magnetic properties，twenty—eight novel complexes have been synthesized and all of their single crystals wit}l novel structures have been determined by X—ray diffraction technique．Some of the complexes have been characterized by element analyses，IR，Uv—visble，ESR， variable-temperature magnetic susceptibility,variable-field magnetic susceptibility． Some parameters characterizing magnetic properties have been evaluated from magnetic measurements and theoretical methods． Five novel one—dimensional chain complexes with nitronyl nitroxide radical have been characterized structurally and magnetically．A u 1 10也bridged ferromagnetic cobalt0I)complex with nitronyl nitroxide radical has been synthesized，and investigated theoretically by temperature-dependent magnetization，field—dependent magnetization and Brillouin function．An one—dimensional ferromagnetic chain complex with diamagnetic metal Ag(I)ion and nitronyl nitroxide radical has been investigated．Some valuable experimental result about magnetic exchange interaction between nitronyl nitroxide radicals through diamagnetic metal ion has been obtained． Quantum Chemistry Caculations have been use