烧结NdFeB材料镀层失效的分析和预防.pdf

表面技术 第46 卷 第4 期 ·12 · SURFACE TECHNOLOGY 2017 年4 月 烧结 NdFeB 材料镀层失效的分析和预防 1 1 1 1 2 2 南海洋 ，刘慧丛 ，李卫平 ，朱立群 ，张健 ，杜凡 （1.北京航空航天大学，北京 100191；2.京磁材料科技股份有限公司，北京 101300） 摘 要：目的研究烧结NdFeB 材料镀层失效的问题。方法 通过SEM 和电化学的测试方法，包括极化曲线、 交流阻抗和零电荷电势等确定失效的主要原因是镀层内部NdFeB 的腐蚀，降低了镀层结合力。结果 植酸衍 生物可以有效抑制镀层内部的腐蚀。吸附能G0 为27.93 kJ/mol ，表明这种吸附是以物理吸附为主，化学吸 ads 附为辅。结论 缓蚀作用机制主要是植酸衍生物分子吸附在NdFeB 表面，阻止了腐蚀的发生。 关键词：NdFeB ；镀层；植酸衍生物；腐蚀；缓蚀；吸附 中图分类号：TG174.4 文献标识码：A 文章编号：1001-3660(2017)04-0012-04 DOI ：10.16490/j.cnki.issn.1001-3660.2017.04.003 Failure Analysis and Prevention of Coating on Sintered NdFeB 1 1 1 1 2 2 NAN Hai-yang , LIU Hui-cong , LI Wei-ping , ZHU Li-qun , ZHANG Jian , DU Fan (1.Beihang University, Beijing 100191, China; 2.Jingci Material Science Co., Ltd, Beijing 101300, China) ABSTRACT: The work aims to study failure of coating on sintered NdFeB. Aided by SEM and electrochemical test methods including polarization curves, AC impedance and zero charge potential, main reason was testified to be NdFeB corrosion inside the coating, which reduced the coating adhesion. Phytic acid derivatives could efficiently inhibit corrosion inside the coating. 0 The G was 27.93 kJ/mol. The was mainly physical adsorption and partly chemical adsorption. The corrosion inhibition me- ads chanism is the adsorption of phytic acid derivatives on NdFeB, which prevents the occurrence of