三维石墨烯宏观体的制备及超级电容性能-华东理工大学学报.PDF

DOI:10.14135/j.cnki.1006-3080. 20180530001 三维石墨烯宏观体的制备及超级电容性能 1 2 3 王 森 ，王永香 ，李金霞 (1.山东大学微生物技术研究院，青岛266237；2.上海市质量监督检验技术研究院，上海 201114；3.华东 理工大学化学与分子工程学院，上海200237） o 摘要：在油浴90 C 和常压下，采用化学还原法和冷冻干燥的方法合成了三维石墨烯宏观体(3D-RGM) 。 经过自组装得到的3D-RGM 具有相互连接的介孔-大孔开放性孔结构, 孔壁则是由单层或多层具有褶皱特征 结构的还原石墨烯片组成。3D-RGM 具有很好的可压缩性，将其作为超级电容器的电极材料时可采用直接 压片法制备工作电极。3D-RGM 电极在0.1 A/g 电流密度下的比电容达到150 F/g ，是较优良的超级电容器 材料。 关键词：三维石墨烯；超级电容器；自组装 中图分类号：O646 文献标志码：A Synthesis and Supercapacitive Performance of Three-Dimensional Graphene Macroform 1 2 3 WANG Sen , WANG Yong-xiang , LI Jin-xia （1. State Key Laboratory of Microbial Technology of Shandong University,Qing dao, 266237,China;2. Shanghai Institute of Quality Inspection and Technical Research, Shanghai 201114, China;3 .School of Chemistry and Molecular Engineering, East China University of Science and Technology, Shanghai 200237,China ） Abstract: In recent years, three-dimensional graphene networks have attracted much attention for both fundamental science and applied research in environment, energy, sensing fields as adsorbents, electrochemical double-layer capacitors or electrode material, owing to its high specific surface areas, large pore volumes, strong mechanical strengths and fast mass and electron transport. Assembling micrometers size graphene oxide sheets into macroscopic architectures is a challenge for graphene fabrication. In this work, a mild method for preparation of three-dimensional graphene macroform (3D-RGM) is developed via an in