络合法从大豆油脱臭馏出物中提取植物甾醇的工艺.pdf

20 4 No.4 Vol.20 2006 8 Journal of Chemical Engineering of Chinese Universities Aug. 2006 1003-9015(2006)04-0571-05 , , , , ( , 310027) E 1:1 1:24:140 1 h96% 75% ; β-; ; ; TQ645.98 TQ028.8 A Extraction of Phytosterols from Soybean Oil Deodorizer Distillates by Adduct Formation with Calcium Chloride YANG Yi-wen, FU Xiao-feng, WEI Zuo-jun, SU Bao-gen, REN Qi-long (National Laboratory of Secondary Resources Chemical Engineering, Department of Chemical and Biochemical Engineering, Zhejiang University, Hangzhou 310027, China) Abstract: A novel process of extracting the phytosterols from the soybean oil deodorizer distillates was proposed as follows. After extracting the vitamin E from the soybean oil deodorizer distillates, the free sterols will be released by the transesterification of the sterol esters existed in the remained deodorizer distillates at first, and then the free sterols will be extracted by the adduct formation with calcium chloride. Finally, the adducts will be decomposed to obtain phytosterols. The optimal operation conditions for the process proposed were studied and were confirmed as follows. Using the ethyl acetate as aprotic solvent and the methanol as protic solvent, the mass ratio of ethyl acetate to the remained distillates is 1:1, and the methanol to calcium chloride is 1:2, the molar ratio of calcium chloride to phytosterol is 4:1, the adductive extraction temperature is 40 and the extraction time is 1 h, respectively. Under the above optimal conditions, the content of the phytosterols in the product can be more than 9