锂离子电池碳负极中边缘碳及表面碳原子含量的理论计算.pdf

第 38 卷第 2 期 中南大学学报( 自然科学版) Vol.38 No.2 2007 年 4 月 J. Cent. South Univ. (Science and Technology) Apr. 2007 锂离子电池碳负极中边缘碳及 表面碳原子含量的理论计算 张 宝，郭华军，李新海，王志兴，彭文杰 ( 中南大学 冶金科学与工程学院，湖南 长沙，410083) 摘 要：通过理论分析与计算得到边缘碳及表面碳原子含量的表达式。分析了石墨微晶结构与成键特征，研究了 石墨微晶中边缘碳原子与基平面碳原子的电化学特性。结果表明：边缘碳原子比基平面碳原子更易于与其他原子 或基团形成较为稳固的联接，电化学反应活性较高；在首次充电过程中，边缘碳原子附近电解质的分解与 SEI 膜 成膜反应速度较快，有利于形成联接较为紧密的 SEI 膜；建立了紧密堆砌的正六棱柱颗粒模型，推导出理想石墨 中边缘碳原子及表面碳原子含量与微晶参数、颗粒尺寸之间的关系式。通过引入适当因子，修正了实际石墨颗粒 与理想石墨在结构、形貌、孔隙率等方面的差别，得到的表达式可适用于石墨、无定形碳及改性碳等多种碳材料 碳原子含量的计算。 关键词：锂离子电池；负极；碳；石墨 中图分类号：TM912.9 文献标识码：A 文章编号：1672-7207(2007)02−0251−05 Theoretical calculation of fraction of carbon atoms on surface and edge for carbon anode of lithium ion battery ZHANG Bao, GUO Hua-jun, LI Xin-hai, WANG Zhi-xing, PENG Wen-jie (School of Metallurgical Science and Engineering, Central South University, Changsha 410083, China) Abstract: The fractions of carbon atoms on the surface and edge were obtained by theoretical analysis and calculation. The electrochemical characteristics of carbon atoms on the edge and basal plane were determined by analyzing structure of graphite crystal and bond of different carbon atoms. The results show that the atoms on the edge are more active for electrochemical reactions and tend to form stable bond with other atoms and groups. In the initial charge, the electrolyte decomposition and formation of solid electrolyte interface (SEI) on the edge are faster, and tighter SEI is formed there. A hexagonal close-packed model for graphite particle was developed. The fraction of carbon atoms on the surface and edge was