澳门岛海洋大气中甲磺酸粒子的研究.PDF

2008,28(1) 7~11 China Environmental Science 1,2* 3 , (1., 510640 2., 510640 3., 510640) ,(MSA)pH . ,MSA 6.7×1011 11 3 ~24.5×10 nmol/m , 9.3%~33.8%,pH 1.63~2.51, 1.1294~1.4371µm.,MSA ; ,MSA ,,,pH ;,MSA ,. X502A 2008 Study on methane sulfonic acid particles in the marine atmosphere of Macao Island. ZHANG Bao-an1,2 *, QIAN Gong-wang3 (1.College of Chemical Science, South China University of Technology, Guangzhou 510640, China 2.College of Environment Science and Engineering, South China University of Technology, Guangzhou 510640, China 3.State Key Laboratory of Pulp and Paper Engineering, South China University of Technology, Guangzhou 510640, China). China Environmental Science, 2008,28(1)7~11 Abstract The concentration and percentage, diameter, pH value, and general variational characteristics of methane sulfonic acid (MSA) particles collected from the marine atmosphere of Macao Island of China were studied using the thin film method for single particle detection. The concentration of MSA particle in the atmosphere was 6.7×1011 ~24.5×1011 nmol/m3, the number were 9.3%~33.8%, the pH value 1.63~2.51, and the equivalent diameter 1.1294~1.4371µm. There was obvious seasonal and daily variations of these parameters. The concentration and number percentage of MSA particle reached their maxima in summer; the equivalent diameter and acidity of MSA particle increased with the decreased of air temperature and increasing of the relative humidity, attaining maximum and minimum respectively in spring. During the day, highest MSA particle concentration appeared in the afternoon and lowest in the morning. Key words methane sulfonic acid particles thin film method marine atmosphere Macao Island (MSA) Saltzman