高效液相色谱法测定柑橘中多菌灵痕量残留量-食品安全质量检测学报.PDF

5 11 Vol. 5 No. 11 2014 11 Journal of Food Safety and Quality Nov. , 2014 /- 周晓洁 1, 2, 赵良忠 1, 2, 3*, 夏 湘 1, 2, 3, 王 丽 1, 2 (1. , 422000; 2. , 422000; 3. , 422000) 摘 要: 目的 /-方法 Cyclone-MCX , , PA ⅡC18 , 结果 1~20 µg/L , Y=0.0921X -0.0016, r=0.9995; 0.1 μg/L(S/N=3); 3 (n=6)86.5%~96.7%; 6 2.34%~3.21%结论 , 关键词: /; ; ; Determination of trace carbendazim in citrus by high performance liquid chromatography with on-line clean-up and solid phase extraction ZHOU Xiao-Jie1, 2, ZHAO Liang-Zhong1, 2, 3*, XIA Xiang1, 2, 3, WANG Li1, 2 (1. Department of Biological and Chemical Engineering , Shaoyang University, Shaoyang 422000, China; 2. Technology Research and Design Center of Hunan Liwen Food Co . Ltd., Shaoyang 422000, China; 3. Soybean Processing Techniques of the Application and Basic Research Base in Hunan Province, Shaoyang University, Shaoyang 422000, China) ABSTRACT: Objective To establish a method for determination of carbendazim in citrus by high perfor- mance liquid chromatography with on-line clean-up and solid phase extraction. Methods After the samples were purified and enriched in the solid phase extraction column Cyclone-MCX, the solid phase extraction column switch to the analysis flow path by switching valve, then let the target analytes flush from the enrich-