大分子缓凝剂对建筑石膏水化进程的影响及缓凝机理-硅酸盐学报.PDF

· 896 · 硅 酸 盐 学 报 2008 年 第36 卷第7 期 硅 酸 盐 学 报 Vol. 36 ，No. 7 2 0 0 8 年 7 月 JOURNAL OF THE CHINESE CERAMIC SOCIETY J u l y ，2 0 0 8 大分子缓凝剂对建筑石膏水化进程的影响及缓凝机理 彭家惠，张建新，陈明凤，吴 莉，瞿金东 (重庆大学建筑材料系，重庆 400045) 摘 要：研究了大分子缓凝剂(骨胶)对建筑石膏水化进程、液相离子浓度与过饱和度及二水石膏晶体形貌的影响，结合X 光电子能谱分析技术对其缓 凝机理进行了分析。结果表明：骨胶能抑制建筑石膏早期水化，使其水化放热减缓，早期水化率降低，凝结时间延长；骨胶对二水石膏晶体形貌影响 较小，但使二水石膏晶体尺度明显增大；骨胶与二水石膏晶核表面钙元素作用，在其表面形成化学吸附层，降低晶核表面能，抑制二水石膏晶核生长， 使建筑石膏水化进程变缓。 关键词：石膏；缓凝剂；水化进程；晶体形貌；缓凝机理 中图分类号：TU526 ；TQ177.3 文献标识码：A 文章编号：0454–5648(2008)07–0896–05 INFLUENCE OF MACROMOLECULE-TYPE RETARDERS ON THE HYDRATION PROCESS OF BUILDING GYPSUM AND ITS RETARDING MECHANISM PENG Jiahui ，ZHANG Jianxin ，CHEN Mingfeng，WU Li，QU Jindong (Department of Construction Materials, Chongqing University, Chongqing 400045, China) Abstract: The effect of macromolecule-type retarder bone glue on the hydration process, ion concentration in liquid phase and super- saturation degree, and crystal morphology of dehydrate of building gypsum was investigated. Furthermore, by using the X-ray photo- electron spectroscopy technique, its retarding mechanism was also studied. The results indicate that the addition of bone glue retards the early hydration of building gypsum, which leads to a delay in the hydration heat evolution. It can also decrease the hydration ratio at in the early stage and the prolong induction period of building gypsum. Bone glue has a minor effect on the crystal morphology of dehydrate and a lower negative effect on the strength of hardened gypsum paste than low molecule-type retarder. But it causes the large crystal sizes. Bone glue interacts with the Ca element on the crystal nuclei surface of dehydrates a