利用电浆处理及接枝聚合丙烯酸改善纤维素表面亲水性Graft.PDF

利用電漿處理及接枝聚合丙烯酸改善纖維素表面親水性 Graft polymerization of Acrylic acid onto Plasma activated Esterification of Cellulose for Improvement of hydrophilic and Moisture Absorption a a a b c 陳克紹 * 、李怡萱 、廖淑娟 、陳素真 、簡志偉 a 大同大學材料工程學系 b 財團法人紡織產業綜合研究所 c 香港理工大學紡織及製衣學系 E-mail: kschen@ttu.edu.tw ABSTRACT: In this study, esterification of cellulose was 術，可增加親水性，並減少製程污染問題以供後續改質 modified by oxygen plasma-activated and isopropyl 需求。在本研究中，利用氧氣電漿處理，使其表面 alcohol plasma depositions of organic film to esterification 活化產生自由基，或由異丙醇電漿沉積有機醇化 of cellulose surface of polymer to improve the hydrophilic. After plasma deposition, the specimens were immersed in 物，之後進行可供 UV 光接枝聚合固定 AAc 5wt%~10 wt% acrylic acid solution followed by （Acrylic acid ）。實驗示意圖如 Fig 1. photo-grafting by UV light. The hydrophilic measure was 實驗 carried out by water contact angle for and the water (1)基材基材及藥品及藥品 基材基材及藥品及藥品 absorption for esterification of cellulose. The water contact 2 a.基材：酯化纖維素(3x3 cm ) angle of IPA plasma was improved from 82.1° to 0°. The b. 沉積單體：氧氣(O gas) 、異丙醇(Isopropanol, IPA ） surface property of esterification of cellulose g-AAc was 2 characterized by FT-IR, SEM, and Moisture Absorption. c.接枝聚合單體：丙烯酸(Acrylic acid,AAc) (2)材料材料製備製備 By oxygen plasma or IPA plasma treatment, after its 材料材料製備製備 moisture rate from 0.77% to increase 1.87%. After plasma a. Plasma CVD(PECVD)於基材表面沉積有機薄膜，使用 deposition grafting polymerization of its moisture even 內部電極式電漿反應器RF 13.56MHz ，氧氣電漿條件： better results.