丙烯酸系列化学品.docxVIP

丙烯酸系列化学品 丙烯酸酯共聚高吸油树脂的合成及性能 201803150174 闫峰，沈一丁收稿日期：；定用日期： 收稿日期：；定用日期： DOI:基金项目：国家自然科学基金(； 陕西科技大学研究生创新基金 作者简介：闫峰(1990－) ，男，硕士生。联系人：沈一丁(1957－) ，男，博士，教授，博士生导师，E－mail:ydshen@sust.edu.cn。 (陕西科技大学 陕西省轻化工助剂重点实验室，陕西 西安 710021) 摘要：采用悬浮聚合的方法，以丙烯酸丁酯(BA)和甲基丙烯酸甲酯(MMA)为单体、过氧化二苯甲酰(BPO)为引发剂、邻苯二甲酸二烯丙酯(DAP)为交联剂、聚乙烯吡咯烷酮(PVP)为分散剂，合成了丙烯酸酯类高吸油性树脂(POA树脂)。采用FTIR对POA树脂进行了表征，并在不同油品中考察了树脂的饱和吸油率、离心保油率。结果表明：两种单体悬浮共聚合成了POA树脂，对多种油品均具有一定的吸收性，但对于不同种类油品的吸收能力并不相同，其饱和吸油率依次为：卤代烃芳香烃丙酮脂肪族烃及环烷烃，进一步的实验发现树脂的饱和吸油率越高，其离心保油率越低。通过TG和重复吸油测试证明了合成的POA树脂在较高的环境温度下能够稳定使用，并能保持较高的饱和吸油（CCl4）率20.13 g/g，重复5次进行吸油，依然保持较高的吸油、保油效率。 关键词：高吸油树脂；吸油能力；饱和吸油率；离心保油率；重复使用；丙烯酸系列化学品 中图分类号： TQ325.7 文献标志码：A 文章编号： Synthesis and Properties of Polyacrylate High Oil Absorption Resin YAN Feng, SHEN Yi-ding。, MA Guo-yan, YANG Kai 。 (Shaanxi Key Laboratory of Chemical Additives for Industry, Shaanxi University of Science Technology, Xian 710021, Shaanxi, China) Abstract: A polyacrylate high oil absorption resin (POA resin) was prepared by suspension polymerization using butyl acrylate (BA) and methyl methacrylate (MMA) as monomers, dibenzoyl peroxide (BPO) as evocating agent, diallyl phthalate (DAP) as crosslinking agent, polyvinyl pyrrolidone (PVP) as dispersing agent. The resulting POA resin was characterized by FTIR. The saturated oil absorption rate and centrifugal oil retention rate of PAO resin were studied in different oil products. The results showed that POA resin was successfully synthesized and had certain absorbability to various oil products, but the oil absorption capacity of different kinds of oil was not the same. The order of saturated oil absorption rate was halogenated hydrocarbonaromatic hydrocarbonacetonealiphatic hydrocarbon and cycloalkane. Further experiments found the higher the saturated oil absorption rate of resin, the lower the centrifugal oil retention rate. Thermogravimetric analysis（TG）and repeat oil absorption test proved that the synthesized POA resin could be used