化学氧化剂对多环芳烃污染土壤的修复效果研究The-山东农业大学.PDF

山东农业大学学报(自然科学版),2016,47(3):378-382 VOL.47NO.3 2016 Journal of ShandongAgriculturalUniversity (Natural Science Edition ) doi:10.3969/j.issn.1000-2324.2016.03.011 化学氧化剂对多环芳烃污染土壤的修复效果研究 * 黎舒雯,陆 敏 ,刘 敏,刘欣然,葛荣荣 华东师范大学地理科学学院; 华东师范大学地理信息科学教育部重点实验室, 上海 200241 摘 要: 本文通过模拟修复实验，研究了类Fenton 试剂和活化过硫酸钠对焦化厂和炼油厂多环芳烃污染土壤的修复效 果。结果表明，焦化厂土壤经类Fenton 和活化过硫酸钠处理后最佳去除率分别为90%和97%，炼油厂土壤经处理后 86% 91% Fenton 的最佳去除率则分别为 和 。两种土壤均表现为活化过硫酸钠的处理效果优于类 试剂，但达到最佳去 除效果时所需的氧化剂剂量不同。且两种氧化剂较安全，不会造成二次污染。氧化剂对NAP、ACY、ACE、ANT 和 BaP 等PAHs 去除效果较好，而FLA、B[b/k]F 等PAHs 的去除率相对较低。焦化厂土壤经处理后，低环PAHs 的去除 率比高环高出5%~39%，而炼油厂土壤的高环PAHs 去除率比低环高出3%~13%。反应后，土壤中有机质的含量也相 应下降。同等剂量下，活化过硫酸钠处理后有机质的降解率比类Fenton 试剂高。 关键词: 多环芳烃; 土壤污染; 氧化剂; 修复 中图法分类号:[TE991.3] 文献标识码:A 文章编号:1000-2324(2016)03-0378-05 The Remedial Effect of Oxidants on Soils Contaminated by PolycyclicAromaticHydrocarbons  LI Shu-wen,LU Min ,LIU Min,LIU Xin-ran,GE Rong-rong Key Laboratory of Geographic Information Science of the Ministry of Education; School of Geography Science/East China Normal University,Shanghai200241,China Abstract: In this paper, the remedial effects of modified Fenton and activated Sodium per-sulfate on the soils contaminated by PAHs from coking plant and oil refinery were studied with a a simulation test.Theresults showed that that for the coking plant soil, the best removal rate of PAHs was 90% by the modified Fenton and 97% by the activated sodium per-sulfate respectively, while in the oil refinery soil that was 86% and 91% respectively.Activated Sodium per-sulfate was better than modified Fenton, but the optimal dosage was different when reaching the best removal efficiency. Both of oxidants were f