杉木炭磺酸的制备及其催化性能研究-中南林业科技大学学报.PDF

第32 卷 第6 期 中 南 林 业 科 技 大 学 学 报 Vol. 32 No. 6 2012 年6 月 Journal of Central South University of Forestry Technology Jun. 2012 杉木炭磺酸的制备及其催化性能研究 1 1 2 2 袁利萍 ，胡云楚 ，徐 琼 ，尹笃林 (1. 中南林业科技大学 材料科学与工程学院，湖南长沙4 10004；2. 湖南师范大学 精细催化合成研究所教育部 化学生物学及中药重点实验室，湖南长沙4 10081) 摘 要：将杉木粉高温热解炭化成可功能化的炭，经发烟硫酸磺化后，得到一类在多种有机合成中有酸催化活 性的质子酸炭材料。考察了炭化、磺化条件对杉木炭磺酸酸量的影响。通过红外光谱、XRD 、元素分析等对炭 磺酸的表征，说明了对杉木炭的磺化改性成功。杉木炭磺酸对Pechmann 缩合反应、酯化反应以及环氧化合物的 醇解反应都具有良好的催化性能。 关键词：杉木；炭磺酸；制备；催化性能 中图分类号：S791.27 ；S785 文献标志码：A 文章编号：1673-923X(2012)06-0184-04 Preparation and catalytic function of Chinese fir char sulfonic acid 1 1 2 2 YUAN Li-ping , HU Yun-chu , XU Qiong , YIN Du-lin (1.School of Materials Science and Engineering, Central South University of Forestry Technology, Changsha 410004, Hunan, China; 2.Institute of Fine Catalysis and Synthesis, Key Lab. Biology Chinese Traditional Medicine Analysis, Hunan Normal University, Changsha 410081, Hunan, China;) Abstract: The functionlized charcoal was prepared by pyrolysis from Chinese fir wood processing residues. The bronsted acid carbon was obtained after the charcoal was sulfonated by fuming sulfuric acid, which have good catalytic activity in a variety of organic synthesis. The effects of the carbonization and sulfonation conditions on the amount of sulfonic acid were investigated. FTIR 、XRD and elemental analysis shows that Chinese fir charcoal retained the benzene ring structure of lignin, and sulfonated groups successfully bonded to the charcoal skeleton. Chinese f