活性炭吸附二苯并呋喃的动力学-环境科学学报.PDF

26 10 Vo.l 26, No. 10 2006 10 Acta Scientiae Circumstantiae O ct. , 2006 , , . 2006. [ J]. , 26( 10): 1695- 1700 L iX, Li Z, Luo L A. 2006. A dsorption kinetics of dibenzofuran on activated carbon[ J]. A cta Scientiae Circum stantiae, 26( 10): 1695- 1700 1, * 2 3 李 湘 , 李 忠, 罗灵爱 1. 肇庆学院轻工化学系, 肇庆 526016 2. 华南理工大学化工与能源学院, 广州 510640 3. 法国国家科研中心化工科学实验室,法国南锡 54001 : : : : Norit RB1M onolith, 2 , . , Langmuir N oritRB1M onolith; ; , . : ; ; ; : 2006) : X131. 2 : A Adsorption kinetics of dibenzofuran on activated carbon 1, * 2 3 LIX iang , LI Zhong , LUO lingai 1. Chem istry Departm ent of Zhaoqing University, Zhaoqing 526061 2. The Institute of Chem icalEngineering, South China University of Technology, Guangzhou 510640 3. Laboratoiredes Sciences du G enie Chmi ique, CNRS, Nancy 54001, rance Received 12 Decenber 2005; received in revised form 17 July 2006; accepted 23 August 2006 Abstract: A gravmi etricm ethod w as adopted to calculate the adsorption isotherm and kinetic curves of dibenzofuran w ithNoritRB1 andMonolith activated carbon. The kinetic curvesw ere fitted by solid phase diffusionm odel to calculate them ass transfer coefficient and diffusion coefficient. The effects of bulk gas concentration, adsorption temperature and initial solid phase concentration on the diffusion coefficientw ere also analyzed. The results show ed that the isotherm dataw erew ell fitted by the L angmuir equation under the studied conditions. The adsorption rate of dibenzofuran on the Norit RB1 andM onolith activated carbonw asm ainly controlled by solid surface diffusion. The higher the adsorption temperaturew as, the larger them ass diffusion coefficientw as. The effects of bulk gas concentr