基于杯4芳烃电化学活性受体的合成、表征及识别性质研究-有机化学专业论文.docxVIP

山东师范大学硕士毕业论文Abstract 山东师范大学硕士毕业论文 Abstract Supramolecular electrochemical recognition is all emerging and interesting subject, which focuses on developing novel redox·active receptors．It is great important to both the field of supramolecular chemistry and practical domain of advanced techniques of ion transport,molecular switch,electrochemical molecular devices and chemical sensors．Therefore，a study on design,synthesis and supramolecular recognition properties of calix[4]arene based redox·active receptors Was carried out．The main results are鹊fonows：’ I．Recent research progress of calixarene based redox-active receptors，including molecular design,chemical synthesis and their supramolecular electrochemical recognition and sensing properties，Was briefly reviewed． 2．Three novd calixarene based redox-active receptors containing tewahedral MoFeCoS cluster cores were prepared via the selective O-dial-kylation,tosylation, iodinafion and isolobal displacement reactions．The electrochemical properties of these receptors were investigated by the cyclic voRammetry and differential pulse voltemmetry techniques． 3．The first examples of 1，2，3-triazole-bridged ferrocene calixarene receptors were synthesized via the click reactions in excdlent yields．The recognition and sensing properties ofthese receptors were studied by the cydic voltamrnetry．It was found that such receptors show a high selectivity towards EC+and H2P04． 4．A total of 16 novel calixarene based receptors were synthesized．Their structl／les were fully cllaragterized by elemental analyses，IR,1H呲13C NMR and MS spectroscopies．鹊well as for one calixarene derivative and two organometallic compounds being determined by X·ray diffraction techniques． Key words：synthesis，supramolecular electrochemical recognition,calixarene，cluster, ferrocene,cyclic voltammetry,differential pulse voRammetry． III 独创声明本人声明所呈交的学位论文是本人在导师指导下进行的研究工作及取得的研究成 独创声明 本人声明所呈交的学位论文是本人在导师指导下进行的研究工作及取得的研究成 果。据我所知，除了文中酶别加以标注和致谢的地方外，论文中不包含其他人已经发表 或撰写过的研究成果，也不包含为