铌钛双稳定430不锈钢高温氧化行为研究-材料研究学报.PDF

第28 卷 第9 期 材 料 研 究 学 报 Vol. 28 No. 9 2 0 1 4 年 9 月 CHINESE JOURNAL OF MATERIALS RESEARCH September 2 0 1 4 铌钛双稳定430 不锈钢高温氧化行为研究 黄训增 杨弋涛 (上海大学材料科学与工程学院 上海 200072) 摘要 以铌钛双稳定430 铁素体不锈钢(NTS430FSS)与SUS 430 铁素体不锈钢(SUS430FSS)为实验材料, 研究了稳定化元素 铌钛对其高温抗氧化性的影响。通过恒温氧化实验得到两种材料的氧化动力学行为曲线, 结合扫描电镜、能谱分析以及X 射线衍射等分析方法探究高温氧化的微观机理。结果表明, 稳定化元素钛可以显著降低单位面积氧化增重, 使得氧化激活 能由72.6 kJ/mol 提高至121.6 kJ/mol 。钛的氧化物镶嵌在氧化膜与基体之间, 提高了氧化膜与基体的附着力, 改善了材料的 高温抗氧化性能。 关键词 金属材料, 铁素体不锈钢, 高温氧化, 铌钛双稳定, 显微组织 分类号 TG 146 文章编号 1005-3093(2014)09-0641-08 High Temperature Oxidation Performance of a Nb and Ti Stabilized 430 Ferritic Stainless Steel HUANG Xunzeng YANG Yitao* (School of Materials Science and Engineering, Shanghai University, Shanghai 200072) Manuscript received March 19, 2014; in revised form June 4, 2014. *To whom correspondence should be addressed, Tel: (021 E-mail: yyt@staff.shu.edu.cn ABSTRACT High temperature oxidation performance of an Nb-Ti-stabilized 430 ferritic stainless steel (NTS430FSS) and SUS 430 ferritic stainless steel (SUS430FSS) was comparatively investigated by means of isothermal oxidation test, metallographic observation, scanning electron microscope (SEM) along with chemical microanalysis by energy dispersive spectrometry (EDS) and X-ray diffraction analy- sis. The results show that the oxidation weight gain was reduced for the steel with Nb and Ti addition. And the oxidation activation energies were 72.6 kJ/mol and 121.6 kJ/mol for the steel without and with Nb an