碱在赤泥中的存在方式及固定方法研究-材料学专业论文.docxVIP

中北大学学位论文 中北大学学位论文 万方数据 万方数据 （3）赤泥中加入不同比例的石灰并在 1200℃下煅烧，生成具有水化活性的 C2S 及 可溶出的铝酸钠，提高了赤泥的活性，最高碱溶出率可达 82.55%。在低龄期时，净浆 试块的强度与碱的溶出率一致，但龄期增长后，C2S 水化程度增大，提高了净浆试块的 强度。 （4）利用粉煤灰在高温养护下与赤泥作用可以降低可溶碱的含量。赤泥与粉煤灰比 例为 1:2.5 时，赤泥的碱溶出率最低；粉煤灰细度越大，赤泥可溶碱的含量越低；随着 养护时间的增加，粉煤灰-赤泥材料中的可溶碱含量降低。经 XRD 检测可知，钠与粉煤 灰溶出的 Al2O3、SiO2 反应生成了不溶的钠系菱沸石。 关键词：赤泥，活化，可溶碱，水合铝硅酸钠，粉煤灰，沸石 The existing form of alkali in red mud and the research of immobilization methods ABSTRACT Red mud is the waste from the refining of bauxite for the production of alumina and have high level of output .It is difficult to effective use of red mud with the high alkali and low active. In the present technological conditions，the principal treatment way of red mud need to be deposited in the open-air place. But it would cause serious problems, like occupation of the land, air pollution. These problems become pressing problems of the day. In accordance with the high alkali of red mud which causes alkali-aggregate reaction and efflorescence. Reference to relevant standards and using XRD, flame photometer and other test resource studied the existence form of alkali(soluble alkali and insoluble alkali) and the proportion. Meanwhile, the dissolving rate of alkali and the compressive strength of cement slurry as the controlling aims to study the variety laws of soluble alkali and insoluble alkali, the activity of red mud with different activation methods(thermal activation and calcining red mud with calcite). According to the principle of phase coupling, this paper study the new technology of fly ash absorb soluble alkali and reduce the content of soluble alkali from red mud with high temperature. Content and fineness of fly ash, curing time were systematically researched in order to research the mechanism of alkali of fly ash. The major conclusions of present paper as follow: The alkali of Bayer red mud can be divide into two parts: one of them is soluble alkali which is the attachment of lye from productive process; another is insoluble alka