甲氧化基萘类标记的荧光水处理药剂的合成-物理化学专业论文.docxVIP

颈±论文串氧基萘粪标记韵荧竞永簸璃药剂韵合成赢箕性毹评定摘要 颈±论文串氧基萘粪标记韵荧竞永簸璃药剂韵合成赢箕性毹评定 摘要 套戏了荧竞挚钵4．军氧基科一(3一二甲氨纂蕊基)萘畿溅眩烯丙基氯豹季铵 盐(4．MNDMAPN．AQ)，采用红外、质谱、核磁等方法对其进行表征，邋j过考察 反应温度、反应时间、物料配眈确定．『反应的最佳条{牛；将上述单体与霹烯酸、 嚣灞酝歉共聚，势碾究了氇稻翳聚合褒律。 文中对该药荆的荧光性能进行评价，探讨了溶液的pH假、聚合物的粘度、 氧化剂、紫外照射簿的因素对荧光强度的影睫。实验结果袭鹪：在pH=7。10的 繇凌串A《轰M／4-MNDMAPN-AQ懿荧竞强度较稳定，霉蔑黻簇裁戆存在对蕻荧 光强度没有影响。氧化剂、紫外拣照射使该物质的荧光强度减弱，在浓度为 lmg／L一10mg／L范围内AA／AM／4-MNDMAPN*AQ荧光强度蚂浓度呈良好的线性 关系。捻溅下鼹为0。5mg／L。 研窳了AA／AM／4一MNDMAPN-AQ的阻撵憔能，并将其与常规阻垢荆HEDP、 PBTCA、HPMA、PAA进行比较。得出聚台物AA／AM／4．MNDMAPN．AQ的加 入量必I弧g／L左右瓣，阻嚣性兢较好，与HEDP、PBTCA、HPMA、PAA}E较， AA／AN彩4-MNDMAPN-AQ豹隧瓣散莱较差。文串还嚣定了黏凄露隧嚣效果豹影 响，结果表明，黏艘越太AA／AM／4一MNDMAPN-AQ的阻垢效果越好。 关键词：荧光聚合物合成性能 评定 碾士论文 碾士论文 译戴蒸蔡粪稼记煎焚毙拳整理药翻舞会成及冀蛙能译定 Abstract A fluoreseem monomer,atlyl chloride quaternary salt of 4一methoxy-N-(3一N7， N-dimethyl-aminopropyl)naphthalimide，was synthesized and characterized by using infrared，mass spectrum，nuclear magnetic resonance in this paper．The optimized condRions were obtained from investigation of reaction time，reaction temperature and material ratio，秘}c so秘l辨蠢z懿i鳓of 4-MNDMAPN-AQ，acrylic acid(AA)and acrylamide(AM)was studied． The fluorescent performance of AA／AM／4一MNDMAPN—AQ was evaluated．The effect ofpH，the viscosity ofpob’龇oxidant and ultraviolet radiation was surveyed， 确eresuRs showedthatthefluorescentintensityofpolymerareconstantatp珏_7～10； m general used iIlllibitors have no influences on the fluorescent intens时and to some extent the oxidants and sunshine would make the fluorescent intensity become weak．；＆catibratiou curve for the determination of AA／AM／4-MNDMAPN-AQ黜 linear ovelthe range from l mg·L”to 10 mg-o‘．Tlle detection limit for AA，AM，4～nN心IDMAPNwAQ is O．5 mg·L一． The performance of scale inhibition Was researched and the results were compared with HEDP,躞麟，HPMA and PAA，髓#test fndicated that the scale inhibition ratio of AA／AM／4·MNDMAPN-AQ is higher when the polymer dosage is 12 mg·L_1：but its scale inhibition ratio is lower than those of HEDP,PBTCA,HPMA and PAA。髓e effect of polymer relative viscosity on t