海水卤水提锂高效吸附剂的合成及应用研究.PDF

2010 3 27 2 M ar. 2010 CHEM ICAL INDUSTRY AND ENG INEERING Vol. 27 No. 2 : 1004- 9533( 2010) 02- 0138- 0 刘骆峰, 张雨山, 黄西平, 张家凯, 王玉琪 ( , 300192) : 高效吸附剂的研究和开发是高镁锂比海水卤水中锂分离提取的关键, 当前最具工业 用前景 的吸附剂为锂锰氧化物离子筛本研究探讨了各合成条件对锂锰氧化物离子筛吸附剂的结构及吸 附性能的影响, 合成出了适用于不同镁锂比及锂浓度海水卤水的高容量吸附剂, 吸附容量最高可达 4102 mg/g, 锰溶损率为 30 %; 此外, 还开展了锂吸附分离的动态模拟试验, 为所合成吸附剂用 于海水卤水提锂的 用研究奠定基础 : 海水卤水; 提锂; 锂锰氧化物离子筛; 吸附 + : TQ 1311 1 : A Synthesis and Application of EfficientAdsorbent for Lithium Extraction from Seawater and Brines LIU Luofeng, ZHANG Yushan, HUANG X ip ing, ZHANG Jiakai, WANG Yuqi (T ianjin Institute of Seaw ater Desa lination andMulti purpose U tilization, State Oceanic Adm inistration, T ianjin 300192, China) Abstract: Research and development of efficient adsorbents are the key to lith ium extraction from seaw a ter and brinesw ith h igh ratio of magnesium to lithium, and the most prom ising adsorbents for industrial app lication now are lithium m anganese oxide ionsieves. In th is paper, the influences of synthetic condi tions on the structures and adsorption properties of lith ium manganese oxide ionsievesw ere d iscussed, and the adsorbentswh ichw ere verified to have h igh capacity cou ld be app lied to seaw ater and brinesw ith different ratios ofmagnesium to lithium and different lithium concentrations. The highest adsorption ca pacity could achieve 4102 mg /g, and its solutionloss rate ofm anganese w as 30 %. Furthermore, dy nam ic smi ulation expermi ents on lithium adsorption w ere carried out, wh ich laid a foundation for the ap p lication research on lith ium extr