洁净钢连铸用复合无碳浸入式水口的研究-材料学专业论文.docxVIP

武汉科技大学硕士学位论文 武汉科技大学硕士学位论文 第1页 洁净钢连铸用复合无碳浸入式水口的研究 摘 要 本工作从材料的中低温烧结性能，材料的热膨胀性能着手，研究了尖晶石材质、刚玉 材质及刚玉一莫来石材质作为浸入式水臼无碳内衬的可能性，研究结果表明： 1)对尖晶石内村而言，随着活性a—A1。0。微粉的增加，试样越容易烧结，且高温热膨胀系 数也越低；分别添加1％的硅粉和1％的si如能很好的促进试样的烧结，并能降低其高 温热膨胀系数。 2)对刚玉内衬而言，随着活性n—A1：02微粉的增加，试样越容易烧结；添加剂Ti0。和硅粉 能很好的改善刚玉材质的烧结性能，并能降低其高温热膨胀系数。 3)对刚玉一莫来石内衬面言，在800C、l000℃烧成下，随着Uf-AS微粉含量的增加，试 样越容易烧结，但在1550℃烧后，由于有较多莫来石的生成产生了较大体积膨胀，使 得试样内部有较多微裂纹的产生，故过多的Uf-AS微粉加入量对提高其强度产生不利 影响； 4)从无碳与铝碳材质的匹配情况来看，添加1％SiO：和2％M90的尖晶石内衬材料与铝碳 本体材料的匹配性能最好，内外层均无裂纹出现。 关键词：浸入式水口无碳材料尖晶石烧结性能 第1I页 第1I页 武汉科技大学硕士学位论文 Study of the Composition Carbon-Free Submerged Entry Nozzles for Continuous Casting of Clean Steel Abstract 111e probability ofthe using ofspinel．corundum—spinel and corundum—mullite carbon-free inside liner of Submerged Entry Nozzle has been studied from the sinterability and thermal expansion ofmaterials in this work．The results were listed foUows： 1)For the inside liner of spinel，with the increasing of the content of active a．A1203，the samples are easier to sinter and the coefticients of thermal expansion also become smaller．The samples containing 1％Si02 l％Si additives have good sinterability and their coefficients of thermal expansion also decreased． 2)For the inside liner of corundum—spinel．with the increasing of the content of activeⅡ -A1203，the samples are easier sinter．Ti02 and Si improve the sintering of corundum and decrease their coe伍cients ofthermal expansion． 3)For the inside liner of mullite，with the increasing of the content of Uf-AS，the samples easier to sinter at 800℃and 1000℃．However too much Uf二AS iS unfavorable to the intensity of the samples at 1 500℃，because Uf-AS make much mullite which produce huge expansion and destroy the structure of samples． 4)For the matching between carbon—free material and aluminum—carbon material．the spinel with l％Si02 and 2％MgO match very well with aluminum—carbon material．and there flaws in the inside liner and outer material． Keywords：SEN Carbon—free material spinel Sintering 武汉科技大学硕士学