高硫煤不同气氛温和热解过程中含硫组分释放规律-中国电机工程学报.PDF

第 31 卷 第 14 期 中 国 电 机 工 程 学 报 Vol.31 No.14 May 15, 2011 24 2011 年 5 月 15 日 Proceedings of the CSEE ©2011 Chin.Soc.for Elec.Eng. 文章编号：0258-8013 (2011) 14-0024-08 中图分类号：TQ 530 文献标志码：A 学科分类号：470·10 高硫煤不同气氛温和热解过程中含硫组分 释放规律的实验研究 张成，李婷婷，夏季，陈刚 (煤燃烧国家重点实验室(华中科技大学) ，湖北省 武汉市 430074) Experimental Research on the Releasing Characteristics of Sulfur-containing Gases in High-sulfur Coal Under Different Atmospheres During Mild Thermal Upgrading ZHANG Cheng, LI Tingting, XIA Ji, CHEN Gang (State Key Laboratory of Coal Combustion, Huazhong University of Science and Technology, Wuhan 430074, Hubei Province, China) ABSTRACT: Mild thermal upgrading before coal utilization is 气氛对于煤中 C-S 键和 C-C 键的断裂具有选择性，综合脱硫 an efficient method for sulfur removal as well as the quality 效率和热值损失分析，发现 4%O2-N2 的微氧化性气氛下， upgrading. Two coal samples with high sulfur content from 400 ℃的热解温度为最佳的燃烧前温和热解脱硫条件。 Guizhou province were selected to investigate the releasing 关键词：燃烧前；温和热解；脱硫；微氧化性气氛 mechanism of different forms of sulfur under different atmospheres during mild thermal upgrading. The study shows 0 引言 that sulfur in coal can be divided into three types: unstable 煤炭资源在利用过程中产生 SO 、NO 以及痕 organic sulfur, pyrite sulfur and stable organic sulfur. Small x x amount of oxygen in the carrier gas can significantly improve 量有害元素汞的排放对人类的生存环境带来了极 the release amount of SO2 in coal especially for the pyrite 大的危害，已成为当今社会关注的热点话题。对煤 sulfur. The breaking of C-C and