界面聚合法制备聚吡咯薄膜及其增长机理研究-材料工程专业论文.docxVIP

万方数据 万方数据 Subject Specialty Name Instructor : Study on Synthesis and Growth Mechanism of Polypyrrole Film with Interfacial Polymerization : Materials Engineering : Lintao Yang (Signature) _____ : Huilu Li (Signature) ___ Qinghao Yang (Signature) _____ Abstract Conductive polymer polypyrrole (PPy) are widely used in supercapacitor electrode materials, electromagnetic shielding and anticorrosion with low cost, high capacity, environment friendly and safe. Compared with many polymerization processes, the study on the growth mechanism of PPy is unpopular at present. Therefore, it is essential to seek appropriate polymerization conditions and methods, and to explore the growth mechanism of PPy feature film summary interface. Interfacial polymerization was utilized to prepare PPy film at 0 ℃ . The growth mechanism of water and oil biphasic PPy film was investigated with the addition of phase transfer catalyst (PTC). The results showed that the growth mechanism of typically aqueous coral PPy and growth process of interface polymerization of PP y film. Meanwhile, nucleation transformation mechanism controlled by defect size was put forward to understand the growth process of PPy in oil. In addition experiment showed that different property PPy films were processed with different kinds of binary non-ionic surfactants. The study had shown that: Pyrrole nucleated and grew into particle PPy, and then the PPy particle deposited on the interface for the density of PPy particle was smaller than that of chloroform. The particle grew again on the surface. When there are bridge-link structures between particles, there was second growth after the bridge- link to achieve the merge of particles on surface. Then the PPy particles accumulated to 2D network, and finally grew to intact PPy film. At the side near oil, when there was no PTC, the PPy film obtained was smooth. As the concentration of PTC increased, there were gibbous structures on the PPy film, and chan