金属四氨基酞菁聚合膜及其与苯胺共聚膜性质的研究-分析化学专业论文.docxVIP

摘 摘 要 摘 要 本文主要研究了两个方面的内容：l、pH值对聚四氨基酞菁钴 (p-CoTAPc)膜电化学、电催化及紫外光谱性质的影响。2、四氨基 酞菁铜与苯胺共聚物的制备及性质的研究。在研究中运用了循环伏安、 紫外光谱、红外光谱、荧光光谱、四探针仪、电子扫描显微镜等表征 手段。研究表明： f1)随着酸度的增加p-CoTAPc氧化还原电位向正电位方向移动， 并且两者存在线性关系，斜率为一61 mV／pH。其催化性质也同时受到酸 度的影响，随着酸度的提高，催化活性增加。催化氧的还原电位与pH 值成线性关系，斜率为一33．34 mV／pH o／在一定缓冲溶液中浸泡的 p-CoTAPc紫外光谱sort带发生蓝移，蓝移程度与pH值有关，其中pH 7时蓝移最小。Sort带的摩尔吸光度的增长不仅与浸泡时间有关，还与 溶液的pH值有关，碱性溶液比酸性溶液增长要快。／6 e- (2)用电化学方法制备四氨基酞菁铜(CuTAPc)与苯胺共聚的高 分子聚合膜(p—CuTAPc．PAN)，对其性质进行了研究，并与聚四氨基 酞菁铜(p—CuTAPc)进行对比o／研究发现：CuTAPc与苯胺共聚为亲 电反应，CuTAPc被接枝到苯胺芳环(苯式结构)的2一位上。 p-CuTAPc·PAN有新的氧化还原峰出现，紫外光谱Q带蓝移，sort带红 移，摩尔吸光系数增高。荧光光谱出现裂分并发生蓝移，发射强度大 幅度提高，半峰宽变窄。电导率出现微弱增加。在扫描电子显微镜下 呈现出大尺寸、致密的菜花状形貌。且苯胺浓度对共聚膜的电化学性 质、紫外光谱、电导率有一定影响。广c、 关键词：四氨基酞菁钴；四氨基酞菁铜；苯胺；r共聚；y电聚合；pH 值；f电化学广电化学催化；i光谱；胤导率 垒!坠翌!! 垒!坠翌!! 一—— Abstract Two aspects were studied in the paper：1．Acidity effect on the characters of electrochemisty,electrocatalyse and UV—Vis spectra of polymeric Cobalt Tetraaminophthalocyanine(p—CoTAPc)．2．Preparation and characters of copper tetraaminophthalocyanine film incorporated with aniline．Cyclic voltammetry,UV—vis，IR and photoluminescence spectra， scanning electron micrograph and four·point probe conductivity measurement were used in the researches．The results herein show： (1)The redox potentials ofp-CoTAPc are shifted to positive direction with the increasing of acidity,and the pH dependence of the redox potentials is一61 mV／pH slope．The electrocatalytic ability increases with increasing of acidity．The reductive potentials for 02 were found to be pH dependent with a slope of．33．34 mV／pH．The sort bonds of p-CoTAPc film soaked in buffer solution are blue shifted．the blue-shifted extent is related to pH value of solution and is the least in pH 7 bu髋r solution．The increasing of sort bond intensity iS not only related to the soaked time but also to pH value of solution，and the increasing extent is faster in the basic solution than in the acid solution． (2)The polymeric copper tetraaminophthalocyanine incorporated with aniline film(p—Cull