金属取代dawson型多元杂多化合物的合成及其催化醇氧化反应性能研究-化学工艺专业论文.docxVIP

AbstractBased Abstract Based on Dawson—type heterop01y conlpOund P2Wl 8，a series of metal-substituted nle laeunary Dawson—type tungstophosphorie and molybdotungstophosphoric were synthesized． The Dawson-type niobium and pyridine-exchanged molybdoVanadophosphate complex was synthesized． The results of IR， UV—Vi s spectroscopy and DTA-TGA confirmed that aIl compounds still remain basicaIly characteristic of the Dawson structure．The Dawson-type compounds were used in the catalytic selective oxidation of benzyl alcoh01 and catalytic activity was jnvestigated systematically． Metal一substituted the lacunary Dawson—type heteropolyanions exhibited high catalytic activity and selectivity for catalytic oxidation of benzyl alcohol with H202．In particularly，值2-M妒2w】7 had a hi曲catalytic activity．The reaction condition and catalytic aGtivity was investigated，and the op“mization reaction conditions were obtained． When H202 was used as the oxidation，water as solvent and metal一Substituted the 1acunary Dawson—type heteropoIyanions m01ybdotungstophosphoric as catalyst， the reaction condition of catalytic oxidation of benzyl alcohol was investigated by orthogonal design．Optimization reaction conditions were obtained through analyzing results of orthogonal design． A se“es of、^，eIIs—Dawson type niobium and py“dine—exchanged molybdovanadophosphate was synthesized and used in the catalytic oxidation of alcoh01．The results indicated that NbH2P2MO】6V2pry had a high catalytic emciency． When NbH2P2M016V2pry was used as catalyst，many primary and secondary alcohols could be conVerted to the corresponding carbonyl compounds with good to excellent conversion and selectivity．Moreover，this biphasic system based on NbH2P2M01 6V2pry permits extensiVe recycling of the catalyst without significant 10ss in actiVity and the uses of water as solvent aIld H202 as oxidant．From our present results，the hi曲 cat“ytic actiVity of NbH2P2Mol6V2pry was probably related to the cooperation of niobium and pyridine an