金属酞菁的合成及应用研究-应用化学专业论文.docxVIP

金属酞菁的合成及应用研究摘要 金属酞菁的合成及应用研究 摘要 本文合成了一系列的金属酞菁(MPc)，包括单、双、三核酞菁钴磺酸盐(s．CoPe、 b-CoPe、t-CoPe)、同核金属酞菁磺酸盐(b—ZnPe、b-MrtPe)、异核金属酞菁磺酸盐 (Co．ZnPe、Co-MnPg、Zn-MnPe)、二羧基金属酞菁(CobcPe)以及四羧基金属酞菁 (FetePe、CotcPe、NitcPc、CutcPc、ZntcPc)。将这些MPe固载于纳米Ti02薄膜上， 制备成功能性复合薄膜，研究了它们在纳米Ti02薄膜上的吸附方式；分析了御c 水溶液、MPe／纳米Ti02薄膜的UV-Ⅵs吸收性能；比较了不同MPe／纳米Ti02薄膜 降解亚甲基蓝(Ⅷ)的光催化和催化活性；利用循环伏安法研究了s．CoPe、CobcPc 和MtcPcl拘氧化还原行为，并组装成相应的染料敏化太阳电池(DSCs)，测量其光 伏性能。 结果表明，金属酞菁可以通过其酞菁环上引入的磺酸基固载于纳米Ti02薄膜 上；在可见光照射和黑暗条件下，MPc／纳米Ti02薄膜均具有降解MB的催化活性， 且多核金属酞菁磺酸盐对MB的光催化和催化活性优于单核金属酞菁磺酸盐 (t-CoPcb-CoPcs-CoPe)；异核金属酞菁磺酸盐，特别是Co-ZnPe的光催化和催 化活性优于同核金属酞菁磺酸盐的(Co．ZnPcCo．MnPcZn—MnPcb．ZnPe b-CoPcb-MnPc)：在MtcPc组装的DSCs@，ZntcPc具有相对高的光电转换效率。 关键词：金属酞菁；合成：纳米Ti02薄膜；催化降解：染料敏化太阳电池 Preparation Preparation and Application of MetallophthaIocyanines ABSTRACT In this thesis，a series of metal(II)phthaloeyanines，including single—nuclear cobalt(II) phthaloeyanine tetrasulphonates(s—CoPe)，bi—nuclear eobalt(II)phthalocyanine hexasulphonates(b-CoPe)，tri-nuclear cobalt(II)phthalocyanine oetastfiphonates (t-CoPe)，homo／heterobinuclear metal(II)phthalocyanine hexasulphonates(b—Zrdc， b—MnPc，Co—ZnPc，Co—MnPc，Zn—MnPc)，bicarboxyl cobalt phthalocyanine(CobcPe) and five tetraearboxymetallophthaloeyanine complexes(FetePc，CotcPc，NitcPc· CutcPe、ZntcPc)，were synthesized and immobilized on nanocrystalline Ti02 thin films．The UV-Vis spectra of MPc in aqueous and MPc／nanocrystalline Ti02 thin films were compared，and the adsorption of M-Pc 011 the nanocrystalline Ti02 flfin films was investigated．The photocatalytie and catalytic activity of various MPc／nanocrystalline Ti02 thin films were evaluated by degradation of methylene blue (MB)aqueous solution with air under visible light irradiation and dark condition．The redox behavior of s-CoPe，CobcPc and MtePc WaS investigated by cyclic voltammetrym，and the photovoltaic performances ofdye—sensitized solar cells(DSCs) with these N口c were measured． The results revealed that various metallophthalocyaninesulphormtes call be firmly immobilized on nano