金属氧化物纳米材料的制备及光学特性研究-光学工程专业论文.docxVIP

万方数据 万方数据 构和立方晶相的 Cu2O 结构。分析 CuO 纳米花和 CuO 纳米线/Cu2O 量子点结构的 PL 谱变化，推测 CuO 纳米线/Cu2O 量子点结构比 CuO 纳米花缺陷少。观察 CuO 纳米花的 Raman 图谱未发现 Cu2O 特征峰，表明其产物为纯 CuO；CuO 纳米线/Cu2O 量子点结构的 Raman 图谱为 Cu2O 的两个特征峰，我们分析 CuO 纳米线/Cu2O 量 子点结构表面 CuO 纳米线稀少，主要成份为 Cu2O 量子点颗粒。 关键词：ZnO 纳米结构阵列，ZnO 纳米刷，CuO 纳米花，CuO 纳米线/Cu2O 量子 点，光学特性 II Abstract Zinc oxide (ZnO) is an important wide band gap n-type semiconductor material, copper oxide (CuO) is an important narrow band gap p-type semiconductor material. Both of them are widely used in photocatalysis, solar cells, field emission devices, sensor and so on. In this paper, Multiform ZnO nanostructures were synthesized by electrochemical deposition method and thermal evaporation method, CuO nanoflowers and CuO nanowires with Cu2O quantum dots nanostructure were prepared by electrochemical deposition method. The obtained products were characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM), energy disperse spectroscopy(EDS), ultraviolet visible absorption (UV-vis)，Raman scattering and photoluminescence (PL) spectroscopy to obtain the structural and optical properties. The main contents are as follows: Multiform ZnO nanostructures array controlled synthesis and optical properties Multiform ZnO nanostructures, such as nanotubes, nanorods with tower-like tips, cone-like tips and groove-like tips, are controllably synthesized by electrochemical deposition method at 60 oC, which is lower compared with the prepared temperatures of reported works. The results of XRD indicate the wurtzite ZnO nanostructures are single-crystalline and grow along the c-axis perpendicularly on the substrate. The band gap of ZnO nanostructures changes from 2.57 to 3.39 eV in UV-vis absorption test. Multiform ZnO nanostructures array are promising candidates for future applications in optoelectronic nanodevices and field emission devices. Preparation, microstructure and spectroscopy of ZnO nanobrushs Two diff