循环流化床电站排放烟尘特性及痕量重金属分析-环境科学学报.PDF

第 24 卷第 3 期 环 　境 　科 　学 　学 　报 Vol . 24 ,No . 3 2004 年 5 月 ACTA SCIENTIAE CIRCUMSTANTIAE May ,2004 ( ) 文章编号 2004 　　　中图分类号 :X523 　　　文献标识码 :A 循环流化床电站排放烟尘特性及痕量重金属分析 徐 　鸿 , 骆仲泱 , 王 　涛 , 王 　鹏 , 高 　翔 , 施正伦 , 岑可法　( 能源洁净利 用与环境工程教育部重点实验室 ,浙江大学热能工程研究所 ,杭州 　310027) 摘要 :对 35 th 循环流化床电厂电除尘器入口和出口的烟气气溶胶进行分级取样 ,得到飞灰浓度和粒度分布以及电除尘器的 分级脱除效率. 电除尘器对 PM10 、PM25 的脱除效率分别为 9434 %和 9138 % ,使部分可吸入烟尘颗粒穿透除尘设备而直接 排放到大气环境中. 同时对不同粒度飞灰中重金属含量进行了测试 ,得到痕量元素浓度从高到低依次为 Ni ,Cr ,Cu ,Cd ,Pb , Hg. 痕量重金属含量与飞灰粒径有一定依附关系 ,其分布规律与煤成分 、锅炉燃烧方式和痕量元素自身的挥发特性等因素有 关. 关键词 :循环流化床电厂 ;飞灰 ;痕量重金属 ;PM10 ;PM25 ;脱除效率 Studies on the characteristics of aerosol and trace metals emitted from a CFB coalf ired power plant ( XU Hong , LUO Zhongyang , WANG Tao , WANG Peng , GAO Xiang , SHI Zhenglun , CEN Kefa 　 Clean Energy Environment Engineering Key Lab of MOE , Institute for Thermal Power Engineering of Zhejiang University , Hangzhou 　310027) Abstract :The emission of primary particulates and trace toxic metals from coal - fired power plants is an important environmental issue . Exper iments were performed in a 35 th circulating fluidized boiler (CFB) power plant , where particulate samples in flue gas were retained at the in let and outlet of the ESP and segregated in a cascade impactor . Sizedependent capture efficiencies of the ESP to flue gas particulates were cal culated , with an average of 94 . 3 % for PM and 91. 4 % for PM respectively. Some fine particles were emitted to the atmosphere directly 10 2 . 5 and formed primary inhalable particles. Concentrations of several trace metals were an