硬脂酸钙稳泡机制及其对发泡水泥保温板泡孔结构的影响-中南大学学报.PDF

第 49 卷第 5 期 中南大学学报( 自然科学版) Vol.49 No. 5 2018 年 5 月 Journal of Central South University (Science and Technology) May 2018 DOI: 10.11817/j.issn.1672-7207.2018.05.005 硬脂酸钙稳泡机制及其对发泡水泥保温板泡孔结构的影响 刘萍，唐爱东，王健雁，艾陈祥，张崇，冼诗翔，潘春跃 ( 中南大学 化学化工学院，湖南 长沙，410083) 摘要：以硬脂酸钙为主稳泡剂制备轻质发泡水泥保温板，通过考察硬脂酸钙对发泡水泥泡沫稳定性、疏水性和泡 孔结构等影响，提出硬脂酸钙在化学发泡水泥中的稳泡机制。研究结果表明：硬脂酸钙在化学发泡水泥中的稳泡 机制为硬脂酸钙吸附在水泥颗粒表面使其呈现部分疏水性，进而吸附在气泡的气液界面上使泡沫达到稳定。优化 稳泡剂成分和用量所制备的高性能轻质发泡水泥保温板符合国家标准要求，产品密度为 220 kg/m3 ，抗压强度为 0.63 MPa，导热系数为 0.042 W/(m·K)，体积吸水率为 9.8% 。 关键词：建筑材料；硬脂酸钙；稳泡剂；发泡水泥保温板；泡孔结构 中图分类号：TQ172.4 文献标志码：A 文章编号：1672−7207(2018)05−1054−08 Foam stabilizing mechanism of calcium stearate and its effects on pore structure of foam cement thermal insulation board LIU Ping, TANG Aidong, WANG Jianyan, AI Chenxiang, ZHANG Chong, XIAN Shixiang, PAN Chunyue (School of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China) Abstract: Light weight foam cement thermal insulation board was prepared by using self-made composite foam stabilizer with calcium stearate as principal component. The foam stabilizing mechanism of the calcium stearate in chemical foaming cement was proposed by studying the effects of calcium stearate on foam stability, hydrophobicity and pore structure. The results show that the foam stabilizing mechanism is that cement particles are firstly absorbed by calcium stearate and then partly presented hydrophobic, and subsequently they are absorbed on gas-liquid interface of the bubbles to achieve a stable equilibrium state of the bubbles. The a