深圳湾及邻近水域总溶解磷的来源和时空分布.PDF

中国环境科学 2015,35(3) ：871~878 China Environmental Science 深圳湾及邻近水域总溶解磷的来源和时空分布 * 张军晓,李绪录 , 肖志建 ( 国家海洋局南海工程勘察中心,广东 广州 510300) 摘要：依据 2000~2012 年每月一次的调查资料,简要描述和讨论了深圳湾及邻近沿岸水域中总溶解磷(TDP)质量浓度的时空分布,并结合现 场盐度和溶解无机磷(DIP)实测数据探讨 TDP 的组成和来源以及 DIP 和溶解有机磷(DOP)之间的转化.结果表明,深圳湾和珠江口东南部沿 岸 TDP 质量浓度分别为(0.26±0.22)和(0.05±0.02)mg/L.研究期间,珠江口东南部沿岸 TDP 质量浓度的年内和年际变化不大,趋势平稳.在深圳 湾, 由于受到周边陆源排放的影响,TDP 质量浓度在丰水期较低,枯水期较高,且在 2000~2004 年呈上升趋势,从 0.24mg/L 上升至 0.33mg/L, 而在 2005~2012 年则呈下降趋势,从 0.33mg/L 下降至 0.16mg/L.研究海区中的 TDP 具有“保守性”,主要来自陆源排放.依二元混合质量平衡 模式估算的珠江口东南部沿岸 TDP 的陆源质量分数约为 53.9%,而深圳湾的均大于 80%. TDP 的赋存形态从河口的以 DIP 为主逐渐转变至 近外海的以 DOP 为主,可能暗示磷从河口向海迁移期间,复杂的生物地球化学过程使 DIP 转化为 DOP 的速率大于 DOP 转化为 DIP 的速率. 关键词：总溶解磷(TDP) ；分布；组成；来源；沿岸水；深圳湾；珠江口 中图分类号：X55 文献标识码：A 文章编号：1000-6923(2015)03-0871-08 Temporal and spatial distributions and sources of total dissolved phosphorus in the Shenzhen Bay and adjacent * coastal waters. ZHANG Jun-xiao, LI Xu-lu , XIAO Zhi-jian (South China Sea Marine Engineering Surveying Center, State Oceanic Administration, Guangzhou 510300, China). China Environmental Science, 2015,35(3)：871~878 Abstract ：Based on the data obtained from monthly cruises from 2000 to 2012, temporal and spatial distributions of the total dissolved phosphorus (TDP) concentration in the Shenzhen Bay and the coastal southeastern Pearl River Estuary were briefly presented and discussed. Composition and sources of the TDP and transformations between the dissolved inorganic phosphorus (DIP) and dissolved organic phosphorus (DOP) were also investigated by combining with measurements of the salinity and DIP. The results showed that the TDP concentration was (0.26±0.22) mg/L in the bay and (0.05±0.02) mg/L in the estuary. The intra- and inter-annual variabili