湿法回流消解-氢化物-原子荧光光谱法测定营养强化剂中总硒含量.PDF

7 5 Vol. 7 No. 5 2016 5 Journal of Food Safety and Quality May , 2016 -- * 姜 新 , 刘德晔 , 刘华良 (, 210009) 摘 要: 目的 --方法 - (4:1, V:V)230 ℃, -; 结果 4.0%, 2.0% 2.0~40.0 ng/mL , 0.9999, 0.028 ng/mL, 93.0%~102.0%, 2.2%(n=6) 结论 , 关键词: ; ; - Determination of total selenium in selenium nutrition enhancer by refluxing wet digestion-hydride generation-atomic fluorescence spectrometry * JIANG Xin , LIU De-Ye, LIU Hua-Liang (Jiangsu Provincial Center for Disease Control and Prevention, NanJing 210009, China) ABSTRACT: Objective To establish a method for the determination of total selenium in nutrition enhancer by hydride generation-atomic fluorescence spectrometry (HG-AFS) with refluxing wet digestionMethods The nitric acid-perchloric acid (4:1, V:V) was used as the digestion system with reflux digestion temperature of 230 ℃. Samples were detected by the method of hydride generation-atomic fluorescence spectrometry. And then the effects of digestion system, reducing agent and masking agent on fluorescence intensity were investigated. Results The fluorescence intensity was the strongest using 4.0% hydrochloric acid as acid medium and 2.0% potassium borohydride. Selenium had a good linear