湿法纺聚丙烯腈原丝的微观结构分析.PDF

50 / 2009 7 M icrostructure of PA N Precursor Fiber s in Wet-spinning , , ( , 250022) GE H e-yi, L U H ua- shi, CH EN Juan ( Schoo l of M at erial Science and Eng ineering , U niversity of Jinan, J inan 250022, China) : ( PA N) , PA N , P A N , , , , , P A N : P AN ; ; ; : T Q342. 31 : A : 1001-4381( 2009) 07- 0050- 04 Abstract: T he mo rpholo gy and t he structural int errelat ionship of PA N f ibers in w et- spinning have been analyzed by the m eans of Scanning Electro n M icrosco pe ( SEM) and T ransmission Electro n M-i croscopy ( T EM) . T he result s indicated that the structure of PA N precurso r f ibers w as inher it ed f rom that of nascent f ibers . P A N precursor f ibers w ere composed of f our part s. T he sheet-like skin w hich had high crystallizat ion and hig hly or iented structure w as compact and hom ogeneous. T he core w hich had low cr yst allizat ion w as loose and disor derly. Meanw hile, t he precursor fiber s had a pillar-like lay- ered structure along the f iber ax is. From the skin t o the endothecium, the average thickness of each layer increased gradually. Furthermore, a structural model of PA N precursor fibers has been established. Key words: PA N ; m orpho logy ; structure; m odel PA N 1 [ 1] , , 1. 1 [ 1- 3] , [ 4- 9] ( DM SO, 80% , ) P A N PA N